The obligately autotrophic acidophile Thiobacillus ferrooxidans was grown on elemental sulfur in anaerobic batch cultures, using ferric iron as an electron acceptor. During anaerobic growth, ferric iron present in the growth media was quantitatively reduced to ferrous iron. The doubling time in anaerobic cultures was approximately 24 h. Anaerobic growth did not occur in the absence of elemental...

We study both theoretically and experimental1 the luminescence in non-intentionally but heavily p-doped GaAs quantum wells of 55 and 1501 width. At T=2K the PL spectra under cw excitation present an excitonic peak and a broad acceptor band. Time-resolved optical pumping of the acceptor line allows us to measure the free electron spin relaxation time. We have investigated its temperature depende...

To analyse the electrocatalytic oxidation of carbon monoxide by Rh porphyrins, we isolated a CO-adduct of Rh octaethylporphyrin, and examined its properties and reactivity by IR, NMR, and X-ray crystallographic analyses. The results indicate that the CO adduct of Rh octaethylporphyrin is vulnerable to nucleophilic attack by H2O. The CO-adduct was easily oxidized by an electron acceptor (1,4-nap...

Emission from the excited terminal states of bound exciton-donor complexes has been observed in several I I — V I compounds. Studying these optical transitions allows one to determine the donor ionization energies, the electron effective masses as well as the electron (/-values in these materials. A good theoretical fit to the experimental data was obtained, using the effective mass approximati...

A novel solution-processable non-fullerene electron acceptor 6,6'-(5,5'-(9,9-dioctyl-9H-fluorene-2,7-diyl)bis(thiophene-5,2-diyl))bis(2,5-bis(2-ethylhexyl)-3-(thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione) (DPP1) based on fluorene and diketopyrrolopyrrole conjugated moieties was designed, synthesized and fully characterized. DPP1 exhibited excellent solubility and high thermal stability ...

Understanding the charge-separation mechanism in organic photovoltaic cells (OPVs) could facilitate optimization of their overall efficiency. Here we report the time dependence of the separation of photogenerated electron hole pairs across the donor-acceptor heterojunction in OPV model systems. By tracking the modulation of the optical absorption due to the electric field generated between the ...

Molecular design: Employing electro-copolymerization, we use benzodithiophene-S,S-tetraoxide (BDTT) as an electron acceptor to yield promising electronically conducting polymers (ECPs).

The dissociation of photogenerated excitons and the subsequent spatial separation of the charges are of crucial importance to the design of efficient donor-acceptor heterojunction solar cells. While huge progress has been made in understanding charge generation at all-organic junctions, the process in hybrid organic:inorganic systems has barely been addressed. Here, we explore the influence of ...

INTRODUCTION Plant microbial fuel cells (P-MFCs), and more general sediment microbial fuel cells, make use of electricigenic metabolism of microorganisms in anoxic soils and sediments. Electricigenic microorganisms are able to respire organic carbon from the soil or sediment with an electrode as final electron acceptor [1]. In this work, the focus is on the anode buried in the sediment, the ele...

Oxidation reactions are highly important chemical transformations that still require harsh reaction conditions and stoichiometric amounts of chemical oxidants that are often toxic. To circumvent these issues, olefins oxidation is achieved in mild conditions upon irradiation of an aqueous solution of the complex [Ru(bpy)3 ](2+) and the enzyme laccase. Epoxide formation is coupled to the light-dr...