Molecular junctions formed using the scanning-tunneling-microscope-based break-junction technique (STM-BJ) have provided unique insight into charge transport at the nanoscale. In most prior work, the same metal, typically Au, Pt, or Ag, is used for both tip and substrate. For such noble metal electrodes, the density of electronic states is approximately constant within a narrow energy window re...

A highly selective copper (II) coated graphite sensor was prepared by 1,13-bis(8-quinolyl)- 1,4,7,10,13-pentaoxatridecane (kryptofix 5) as a supramolecule ionophore into plasticized polyvinyl chloride (PVC) membrane. The best response characteristic was observed using the membrane composition of PVC = 30.0 mg, dioctyl sebacate (DOS) = 63.5 mg, palmitic acid (PA) = 3.0 mg and kryptofix 5 = 3.5 m...

0.1016/j.nanoen.2 lsevier Ltd. All rig thor. [email protected] Abstract Organic electroactive materials derived from biomasses are promising candidates for next generation rechargeable batteries due to the low cost, sustainability and environmental benignity. Since organic materials have very low electronic conductivity, they are normally synthesized into nano-scale and mixed with conductive carbon...

This article is a report on a novel and high-stability biosensor with minor interference effects of surface modification of working electrode with β-Ga2O3 nanowires (NWs) on choline oxidase biosensor were investigated in an electrochemical detection system. β-Ga2O3 NWs were materialized on the silicon substrate in a catalyst-free growth mechanism. The β-Ga2O<sub...

The electrochemical sensor for detecting hydrogen sulfide was fabricated. H2S gas molecules pass through polytetrafluoroethylene membrane with 0.22 mm pore size. Carboxylated multi-walled carbon nanotubes (MWCNTs-COOH) were used to fabricate working and counter electrodes. It can be seen from Field Emission Scanning Electron Microscopy (FESEM) images of the working electrode that...

BACKGROUND Although the intensity of neurostimulation (i.e., charge) is a product of current intensity and pulse duration, the effects of the latter on the amplitude of evoked response and subjective discomfort are unknown. Therefore, the authors investigated the effects of current intensity and pulse width, and their interaction with electrode placement and polarity, on force translation (FTR)...

A new PVC membrane mercury(II) ion electrode based on N,N-dimethylformamide-salicylacylhydrazone (DMFAS) as an ionophore is described, which shows excellent potentiometric response characteristics and displays a linear log[Hg(2+)] versus EMF response over a wide concentration range between 6.2 x 10(-7) and 8.0 x 10(-2) M with a Nerstian slope of 29.6 mV per decade and a detection limit of 5.0 x...

A new PVC membrane electrode for the triiodide ion based on a charge-transfer complex of iodine with 7,16-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane as a membrane carrier was prepared. The electrode exhibits a Nernstian response for triiodide ions over a wide concentration range (1.0 x 10(-1)-1.0 x 10(-5) M) with a slope of 59.3 +/- 0.9 mV decade(-1) and a detection limit of 6.3 x 10...