Different types of charge storage mechanisms at unmodified graphite vs. glassy carbon electrodes in acid sulphate supporting solution containing potassium hexacyanoferrate (II) redox active electrolyte, have been revealed by electrochemical impedance spectroscopy and supported by cyclic voltammetry experiments. Reversible charge transfer of Fe(CN)6 redox reaction detected by assessment of CVs o...

the synthesis of polyaniline- fe2o3 nanocomposite coating on aluminum alloy 5052 (aa5052) surface has been investigated by using the galvanostatic method. the anticorrosion performance of polyaniline-fe2o3 coating was investigated in 3.5% nacl solution by the open- circuit potential (ocp), tafel polarization technique and electrochemical impedance spectroscopy (eis). the corrosion rate of polya...

one of the problems in the case of stainless steels is their low corrosion resistance against pitting corrosionin chloride containing environments, thereby leading to severe damage to industries. in this research, the pitting corrosion of 304 austenitic stainless steel was studied in 3.5% nacl solution at room temperature (25˚c) by performing electrochemical measurements (containing cyclic pola...

In recent years, electrochemical supercapacitors have received considerable attention from many researchers. Metal oxides such as chromium oxide with high redox activity, high specific capacity, and excellent reversibility are suitable alternatives to ruthenium oxide in supercapacitor applications. In this study, first, graphene oxide (GO) was synthesized by the modified Hummers method. The syn...

The effect of chloride ions concentration on the electrochemical behavior of AISI 410 stainless steel in the simulated concrete pore (0.1 M NaOH + 0.1 M KOH) solution was investigated by various electrochemical methods such as Potentiodynamic polarization, Mott–Schottky analysis and electrochemical impedance spectroscopy (EIS). Potentiodynamic polarization curves revealed that increasing chlori...

This paper deals with the problem of estimating the state of charge (SOC) of lithium-ion batteries. Based on the analysis of the impedance spectra obtained by electrochemical impedance spectroscopy (EIS), a simplified battery impedance model is derived with the constant phase element (CPE). To interpret the impedance model, a fractional order calculus (FOC) method is introduced to model the CPE...

Hitherto zeolite formation has not been fully understood. Although electrochemical impedance spectroscopy has proven to be a versatile tool for characterizing ionic solutions, it was never used for monitoring zeolite growth. We show here that EIS can quantitatively monitor zeolite formation, especially during crucial early steps where other methods fall short.

Copper-bearing intrauterine devices(Cu-IUDs) are being increasingly used all over the world. However, the dissolution of copper in the presence of proteins is not well characterized. Here, with open circuit potential, electrochemical impedance spectroscopy measurements and potentiodynamic polarization test, the corrosion behavior of copper samples in different single-protein simulated uterine s...

The aim of this study is to elaborate a simple and sensitive electrochemical immunoassay using ferrocenecarboxylic (Fc-COOH)-doped silica nanoparticles (SNPs) as an immobilized affinity support for cancer antigen 15-3 (CA 15-3) detection. The Fc-COOH-doped SNPs with redox-active were prepared by using a water-in-oil microemulsion method. The use of colloidal silica could prevent the leakage of ...