A method for quantitative determination of magnetization exchange rate constants (cross-relaxation and chemical exchange) from a series of two-dimensional exchange spectra is presented. The method, the least error matrix analysis (LEMA), combines a series of full matrix calculations at different mixing times in a least-squares manner. LEMA embodies the principal advantages of full-relaxation ma...

Molecular dynamic simulations were carried out on rigid diatomic molecules, which exhibit both α (structural) and β (secondary) dynamics. The relaxation scenarios range from onset behavior, in which a distinct α process emerges on cooling, to merging behavior, associated with two relaxation peaks that converge at higher temperature. These properties, as well as the manifestation of the β peak a...

Recent works on constraint relaxation [Jussien, 1997; Jussien and Boizumault, 1997b] provided the decorum system (Deduction-based Constraint Relaxation Management). That system can be seen as an integration of arc-consistency within the dynamic backtracking algorithm [Ginsberg, 1993]. Dynamic backtracking replaces the backtracking process by a much less blind behavior that consists in local mod...

In this article, it is demonstrated that current methods of modelling plasticity as the collective motion of discrete dislocations, such as two-dimensional discrete dislocation plasticity (DDP), are unsuitable for the simulation of very high strain rate processes (106 s−1 or more) such as plastic relaxation during shock loading. Current DDP models treat dislocations quasi-statically, ignoring t...

Abstract. The relaxation spectrum is an important tool for studying the behaviour of viscoelastic materials. The most popular procedure is to use data from a small-amplitude oscillatory shear experiment to determine the parameters in a multi-mode Maxwell model. However, the discrete relaxation times appear nonlinearly in the mathematical model for the relaxation modulus. The indirect calculatio...

Dynamic mechanical relaxation is a fundamental tool to understand the and physical properties of viscoelastic materials like glasses. Mechanical spectroscopy shows that high-entropy bulk metallic glass (La30Ce30Ni10Al20Co10) exhibits distinct β-relaxation feature. In present research, dynamic analysis thermal creep were performed using this material at temperature domain around β relaxation. Th...

We study the interaction between an AFM tip and a soft viscoelastic surface. Using a multifrequency method we measure the amplitude-dependence of the cantilever dynamic force quadratures, which clearly show the effect of finite relaxation time of the viscoelastic surface. A model is introduced which treats the tip and surface as a two-body dynamic problem with a nonlinear interaction depending ...

The interpretation of residual dipolar couplings in terms of molecular properties of interest is complicated because of difficulties in separating structural and dynamic effects as well as the need to estimate alignment tensor parameters a priori. An approach is introduced here that allows many of these difficulties to be circumvented when data are acquired in multiple alignment media. The meth...

Lagrangian relaxation technique is successfully applied to solve sequence dependent setup time flowshop problem to minimize the total weighted tardiness. The relaxed problem can be decomposed into each job-level subproblem that can be effectively solved by dynamic programming. Two types of the additional constraints for the violation of sequence dependent setup time constraints are imposed to t...