The asymmetric unit of the title complex, [Co(DMF)(6)](ClO(4))(2) (DMF = N,N-dimethyl-formamide, C(3)H(7)NO), consists of two half complex cations with the Co(2+) metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co(2+) ion is coordinated by six mol-ecules of DMF in a slightly distorted octa-hedral geometry. The crystal structure is mainly stabi...

The structures of micelles of the surfactant polysorbate 80 (Tween 80) in 0-50% aqueous N,N-dimethylformamide (DMF) solutions (pH 7.2, ionic strength 2.44 mM) were investigated by means of small-angle X-ray scattering. At all the tested DMF concentrations, core-shell cylinder micelles formed; that is, increasing the concentration of DMF did not result in changes in the shape of the micelles. Th...

This paper presents a low-power structure of digital matched filters (DMFs), which is proposed for direct sequence spread spectrum systems. Traditionally, low-power approaches for DMFs are based on either the transposedform structure or the direct-form one. A new hybrid structure that employs the direct-form structure for local addition and the transposed-form structure for global addition is u...

We examine the completeness of death reporting in the Social Security Administration's Death Master File (DMF) through comparison with deaths by year and age group reported in official U.S. vital statistics. For most years since 1973, results suggest that the DMF includes 93 percent to 96 percent of deaths of individuals aged 65 or older. Although studies have shown that the National Center for...

Digital microfluidics (DMF) is an emerging liquid-handling technology that enables individual control over droplets on an open array of electrodes. These picoliter- to microliter-sized droplets, each serving as an isolated vessel for chemical processes, can be made to move, merge, split, and dispense from reservoirs. Because of its unique advantages, including simple instrumentation, flexible d...

Does Nrf2 help nerves to survive? Dimethyl fumarate (DMF) has recently been approved for the treatment of relapsing-remitting multiple sclerosis (RRMS) after showing beneficial effects on clinical and radiologic endpoints in 2 phase 3 clinical trials. 1,2 While DMF's mode of action is not completely understood, experimental data suggest that putative neuroprotective properties may be mediated b...

The key steps in oligosaccharide synthesis are protectinggroup manipulation and stereoselective glycosylation. Various strategies have emerged to expedite glycosylation, and some of these strategies have been elaborated for automated solid-phase synthesis and one-pot cascade glycosylation. Most glycosylation strategies rely on traditional methods for stereochemical control over glycosidic-bond ...

The first Lewis acid-catalyzed trifluoromethylation reactions of aldehydes with Me3SiCF3 under TiF4/DMF, Ti(O iPr)4/DMF and Cu(OAc)2/dppp/toluene conditions are described. We have successfully applied this methodology to the difluoromethylation of aldehydes using Me3SiCF2SePh, Me3SiCF2P(O)OEt2 and Me3SiCF2SPh.

Electrospun nanofiber membranes are employed in a variety of applications due to its unique features. the nanofibers' characterizations effected by polymer solution. The used solvent for dissolving powder is critical preparing precursor In this paper, Polyacrylonitrile (PAN)-based nanofibers were prepared concentration 10 wt.% using various solvents (NMP, DMF, and DMSO). surface morphology, por...

INTRODUCTION The objective of this pilot study was to compare cerebral gray matter (GM) atrophy over 1 year in patients starting dimethyl fumarate (DMF) for multiple sclerosis (MS) to that of patients on no disease-modifying treatment (noDMT). DMF is an established therapy for relapsing-remitting (RR) MS. METHODS We retrospectively analyzed 20 patients with RRMS at the start of DMF [age (mean...