A strategy for combined experimental and computational screening of candidate carbonaceous materials for capturing highly volatile nerve agents at ambient temperature using physisorption. Based on theoretical calculations of Henry constants and zero-coverage adsorption enthalpies for sarin and DMMP (its common stimulant) adsorbed in model slit-shaped carbon pores at 298 K, we found the followin...

1. 2-Chloro-1-(2,4,5-trichlorophenyl)vinyl dimethyl phosphate (tetrachlorvinphos) is demethylated by mammalian liver supernatant (100000g) protein in the presence of GSH. 2. GSH acts as an acceptor of the transferred methyl group to form S-methyl glutathione. 3. The enzyme that catalyses this reaction is present in the soluble fraction of liver from mouse, rat, rabbit and pig at similar activit...

Hydrogenation reaction with n-heptane on Pt/Al2O3 catalyst was investigated under the steady state condition in a fixed bed reactor. The catalyst was prepared under a variety of conditions, but the one chosen was non-acidic that is not considered a hydrocracking catalyst. The main objective was to vary the selectivity of n-heptane as a function of reaction variables es...

Abstract N -Methylated derivatives of α-tocopheramine, which have preliminarily been shown to good performance as stabilizers cellulose solutions in ionic liquids for production cellulosic manmade fibers, not accessible sufficient amounts by green syntheses. In this study, the -methyl-, , -dimethyl-, and -trimethylammonium α-tocopheramine were synthesized fully analytically characterized. The p...

Within this work, a modified preparation of diethyl 4-azidobenzylphosphonate (L1) is presented and the family 4- or 4′-azido-substituted aromatic phosphonate esters increased by three new ligand platforms: diisopropyl (L2), ((4′-azido-[1,1′-biphenyl]-4-yl)methyl)phosphonate (L3), 4-azido-2,3,5,6-tetrafluorobenzylphosphonate (L4), which exhibit an anomalous splitting N3 stretching vibrations. Su...

Two new phloroglucinol derivatives, mallotophilippen A (1). and B (2). were isolated from the fruits of Mallotus philippensis. These compounds were identified, using chemical and spectral data, as 1-[5,7-dihydroxy-2,2-dimethyl-6-(2,4,6-trihydroxy-3-isobutyryl-5-methyl-benzyl)-2H-chromen-8-yl]-2-methyl-butan-1-one and 1-[6-(3-Acetyl-2,4,6-trihydroxy-5-methyl-benzyl)-5,7-dihydroxy-2,2-dimethyl-2H...

Reaction of tryptamine 1 with dimethyl -3-methoxyallylidenemalonate 2 afforded N?-[4,4-bis (methoxycarbonyl)-1,3-butadienyl] tryptamine 3 which in combination with acetylchloride and pyridine in dichloromethane gave N?, N?-[acetyl]-[(4,4-dinethoxycarbonyl) 1,3butadienyl] tryptamine 4. Treatment of 3 with sodium hydroxide afforded 2H[N-(3-indolyl) ethyl] 2-oxo-3-methoxycarbonyl-1-pyridine 5. Cy...

Transformation of 3-propargylmercapto-6 methyl-1, 2,4-triazin- 5 (2H)- one (1; R=CH3) to 3,6- dimethyl-7H- thiazolo [3,2-b] [1, 2, 4] triazin -7- one (2) is performed under basic condition. The formation of (2) may be mainly due to the high reactivity of acetylenes towards nucleophiles and isomerization of the intermediate. 

A one-pot synthesis ofdimethyl-{3-methyl-2-[(alkoxycarbonyl) anilino]-2,3-dihydro-1Himidazol-1-yl)}-2-butenedioatesanddimethyl-2-[(alkoxycarbonyl)anilino]-2-butenedioates derivatives via reactions between dimethyl acetylenedicarboxylate,1-methylimidazoleand N-phenylcarbamates is described. The mild reaction condition, simple mixing of the starting materials and good yields exhibit the synthetic...

Neutral chloromethylpalladium(II) complexes, [Pd(Cl)(CH3)(L)] (1a-5a) with ligands κ(2)-N^S-2-((3,5-di-tert-butyl-1H-pyrazol-1-yl)methyl)-6-(phenylthiomethyl)pyridine (L1), κ(2)-N^S-2-((3,5-dimethyl-1H-pyrazol-1-yl)methyl)-6-(phenylthiomethyl)pyridine (L2), κ(2)-N^Se-2-((3,5-di-tert-butyl-1H-pyrazol-1-yl)methyl)-6-(phenylselanylmethyl)pyridine (L3), κ(2)-N^Se-2-((3,5-dimethyl-1H-pyrazol-1-yl)me...