Deuterium oxide dilution space (DOS) determination is one of the most accurate methods for in vivo estimation of ruminant body composition. However, the time-consuming vacuum sublimation of blood preceding infrared spectroscopy analysis, which is traditionally used to determine deuterium oxide (DO) concentration, limits its current use. The use of isotope-ratio mass spectrometry (IRMS) to deter...

Oxygen and hydrogen isotope compositions of Earth's seawater are controlled by volatile fluxes among mantle, lithospheric (oceanic and continental crust), and atmospheric reservoirs. Throughout geologic time the oxygen mass budget was likely conserved within these Earth system reservoirs, but hydrogen's was not, as it can escape to space. Isotopic properties of serpentine from the approximately...

The effective interaction potential for charged particles is calculated in the deuterium plasma formed in the surface region of the palladium cathode in the electrolysis of heavy water. It is shown that the Coulomb potential is overscreened producing, at certain distances, an attractive potential between deuterium nuclei pairs and also between the deuterium nuclei and the surface atoms. This be...

Abstract The possibility of estimating groundwater inflow to irrigation drains in Minia, Egypt, using stable isotopes has been explored. The evaporation pan technique described here makes use of small variations in the concentration of naturally occurring stable isotopes (oxygen-18 and deuterium) in irrigation-fed groundwater and surface water as well as agricultural drainage water. The agreeme...

Stable isotope labeling (SIL) still has not been used very much in pediatric and perinatal clinical pharmacology. However, this method has numerous advantages. It allows one to determine the concentration of drugs with great sensitivity, thereby allowing quantification in small amounts of biologic samples. It also allows quantification with great specificity, eliminating interference by drug me...

The reaction of molecular oxygen with a Pd(II)-hydride species to form a Pd(II)-hydroperoxide represents one of the proposed catalyst reoxidation pathways in Pd-catalyzed aerobic oxidation reactions, but well-defined examples of this reaction were discovered only recently. Here, we present a mechanistic study of the reaction of O2 with trans-(IMes) 2Pd(H)(OBz), 1 (IMes = 1,3-dimesitylimidazol-2...

Using the Effelsberg 100-m telescope, sensitive measurements of the H2O megamaser in NGC 3079 are presented. During 2000 – 2001, 'high velocity' features are seen that are red-shifted up to 225 km s −1 with respect to the systemic velocity of the galaxy (VLSR ∼ 1120 km s −1). Symmetrically bracketing the systemic velocity, the H2O emission covers a velocity range of ∼450 km s −1 with only one p...

A fundamental understanding of the interactions between coadsorbed water and hydrogen on metallic surfaces is critical to many chemical processes including catalysis and electrochemistry. Here, we report on the strong and intricate interactions between coadsorbed H/D and water on the close-packed (111) surface of gold. Deuterium isotopic labeling shows H/D exchange in H-D2O and D-H2O systems, i...

The aim of this study was to compare the measurement of deuterium oxide (D2O) directly in pig serum with that in sublimed whole blood. This was to assess whether excluding vacuum sublimation before analysis would cause any significant loss of accuracy in estimates of pig milk intake. Water and serum standards were made in deionized water and serum, respectively, and were assayed with samples un...