The kinetics of Cu(II) interactions with Susquehanna River (mid-Atlantic, USA) particle suspensions using the copper ion selective electrode (Cu-ISE) method indicated that the concentration of Cu2+ in both the suspension and filtrate was kinetically controlled; the reaction of Cu(II) in the suspension was faster than that in the filtrate. Bioassay tests were performed in continuous flow-through...

YHS-domains are small protein modules which have been proposed to bind transition-metal ions like the related TRASH-domains. They are found in a variety of enzymes including copper-transporting ATPases and adenylyl cyclases. Here we investigate a class IIIc adenylyl cyclase from Mycobacterium phlei which contains a C-terminal YHS-domain linked to the catalytic domain by a peptide of 8 amino aci...

A large amount of cotton stalk waste biomass with high cellulose content are incinerated by the farmers causing air pollution. The high cellulose content of cotton stalks can be converted to fermentable sugars by fungal delignification pretreatment of lignocellulosic biomass and enzymatic saccharification. The effect of particle size, moisture content, and media supplements was studied for deli...

Maurotoxin (MTX) is a 34-mer scorpion toxin cross-linked by four disulphide bridges that acts on various K+ channel types. It folds according to an alpha/beta scaffold, i.e., a helix connected to a two stranded beta-sheet by two disulphide bridges. In a former study, various parameters that affect the oxidation and folding of the reduced form of synthetic MTX were investigated in vitro. It was ...

Recently, Cu2-δS and Cu2-δSe were reported to have an ultralow thermal conductivity and high thermoelectric figure of merit zT. Thus, as a member of the copper chalcogenide group, Cu2-δTe is expected to possess superior zTs because Te is less ionic and heavy. However, the zT value is low in the Cu2Te sintered using spark plasma sintering, which is typically used to fabricate high-density bulk s...

The cyclotriveratrylene-type ligands ( )-tris(iso-nicotinoyl)cyclotriguaiacylene L1 ( )-tris(4-pyridylmethyl) cyclotriguaiacylene L2 and ( )-tris{4-(4-pyridyl)benzyl}cyclotriguaiacylene L3 all feature 4-pyridyl donor groups and all form coordination polymers with Cu and/or Cu cations that show a remarkable range of framework topologies and structures. Complex [Cu4Cu II 1.5(L1)3(CN)6]$CN$n(DMF) ...

Eight new -oxamido-bridged copper(II)–lanthanide(III)–copper(II) heterotrinuclear complexes formulated as Cu2(oxmap)2Ln(NO3)3 (Ln = La, Nd, Eu, Gd, Tb, Dy, Ho, Er), where oxmap stands for N,N -bis(2-methyl-2-aminopropyl)oxamido dianions, have been synthesized by the strategy of “complex as ligand”, and characterized by elemental analyses, molar conductivity measurements, IR and electronic spect...

New dinuclear carboranylcarboxylate-bridged and mononuclear copper(ii) compounds containing the 1-CO2H-2-H-1,2-closo-C2B10H10 carborane ligand () have been synthesized from the previously synthesized dinuclear compound [Cu2(μ-L)4(THF)2], . Reaction of with CuSO4 in THF leads to the dinuclear compound [Cu2(μ-L)4(THF)2], . The reaction of with different terminal pyridyl ligands leads to the forma...

Recent evidence suggests that the prion protein (PrP) is a copper binding protein. The N-terminal region of human PrP contains four sequential copies of the highly conserved octarepeat sequence PHGGGWGQ spanning residues 60-91. This region selectively binds Cu2+ in vivo. In a previous study using peptide design, EPR, and CD spectroscopy, we showed that the HGGGW segment within each octarepeat c...

The electropolishing behaviour of 73 brass was studied by means of a rotating cylinder electrode (RCE) in a 70 vol % H3PO4 solution at 27 ◦C. Owing to the formation of a blue Cu2+-rich layer on the brass-RCE, an obvious transition peak was detected from kineticto diffusion-controlled dissolution in the anodic polarisation curve. Electropolishing was conducted at the potentials located at the tr...