Abstract: Electroless Nickel (EN) composite coatings embedded with Cr2O3 and/or MoS2 particles were deposited to combine the characters of both Cr2O3 and MoS2 into one coating in this study. The effects of the co-deposited particles on corrosion behavior of the coating in 3.5% NaCl media were investigated. The results showed that both Ni-P and Ni-P composite coatings had significant improvement...

Solid oxide fuel cells are a potential electrical power source that is silent, efficient, modular, and capable of operating on a wide variety of fuels. Unfortunately, current technologies are severely limited in that they provide sufficient power output only at very high temperatures (>800°C). One reason for this is because the electrodes have very poor (and poorly understood) kinetics. The wor...

For SOFCs to be main means of power generation, they should be able to exploit wide variety of fuels. Among Ni-cermets, Ni-YSZ is the state-of-the-art materials for the anode in SOFC which is the fuel electrode. But sulphur impurity present in different gaseous fuels (e.g Biogas), depending on its concentration, is highly poisonous to the stability and electrochemical performance of the Ni cata...

This study aims to investigate the microstructural alterations, mechanical properties, sliding wear behavior, and corrosion properties of Al-15%Mg2Si composites with different contents yttria-stabilized zirconia (YSZ). YSZ (0, 3, 6, 9 wt.%) were fabricated using stir-casting technique. The characterized by means optical microscopy (OM), scanning electron (SEM) equipped energy-dispersive spectro...

Firstly, the yttria-stabilized zirconia (YSZ) coating and gadolinium zirconate (GZO) with quasi-columnar structure were manufactured by plasma spray physical vapor deposition. At same time, a novel three-dimensional geometrical model was established that could satisfactorily reflect such structural characteristics. Then, based on this model, spatial distribution of pores porosity coatings therm...

Effect of nano-structuration and compounding of YSZ APS TBCs investigated on coating behavior in thermal shock conditions. The coatings were applied on Inconel 738 discs with three different thickness per powder. In order to harmonize the results from the samples, performance factor is defined as a criterion that in the starting of the activity has an amount of about 100 and is reduced after th...

The oxygen tracer diffusion coefficient describing transport along nano-/microscaled YSZ/Sc2O3 multilayers as a function of the thick-ness of the ion-conducting YSZ layers has been measured by isotope exchange depth profiling (IEDP), using secondary ion mass spec-trometry (SIMS). The multilayer samples were prepared by pulsed laser deposition (PLD) on (0001) Al2O3 single crystalline substrates....

Solid oxide electrochemical reactors (SOERs) may be operated in fuel cell (SOFC) or electrolyser (SOE) modes, at temperatures > 800 K, depending on electrolyte and electrode materials. In mode, current densities of ≥ ca. 104 A m−2 are achievable potential differences ideally the thermoneutral values 1.285 V for steam splitting 1.46 CO2 750 °C. As large scale chemical processes general, such req...

Gadolinium zirconate (GZ) is an attractive material for thermal barrier coatings (TBCs). However, a single layer GZ coating has poor cycling life compared to Yttria Stabilized Zirconia (YSZ). In this study, Solution Precursor High Velocity Oxy-Fuel (SP-HVOF) spray was used produce double GZ/YSZ TBC and the performance with YSZ TBC. The temperature behaviour of solution precursor studied, splat ...