the adsorption properties and mechanics of selected endocrine disrupting compounds; 17 β-estradiol, 17 α – ethinylestradiol and bisphenol a on locally available black tea leaves waste and granular activated carbon were investigated. the results obtained indicated that the kinetics of adsorption were ph, adsorbent dose, contact time and temperature dependent with equilibrium being reached at 20 ...

The article analyzes the role of presupposition in the compound-complex sentence. The authors examine the types of presuppositions and minimal compound-complex sentence as a field of presuppositions action. The analysis of these types of sentences by the material of the English language shows that several kinds of presuppositions are realized in them – contact or distant, - developing in the re...

The compound strip method (CSM) for plates is an expansion of the finite strip method (FSM) and was developed to incorporate the effects of the support elements in the analysis of linear elastic plate systems. In this paper the CSM is further expanded to analyze structures such as stiffened plates under loads in the plane of the plate or the so called plane-stress condition. Examples of these t...

Bis(2,4,6-triisopropylphenyl) tellurone (Tip(2)TeO(2)) was prepared, fully characterized by spectroscopic and X-ray crystallographic analyses, as well as theoretical calculations, and found to be an effective oxidizing agent that was capable of converting alcohols into carbonyl compounds under mild reaction conditions.

A remarkable α-effect of silicon has been discovered that results in soft nucleophilicity at the Cγ of 3,3-bis(silyl) allyloxy lithium 1. The addition of 1 to α,β-unsaturated carbonyl compounds, including enals, proceeds in a 1,4- over 1,2-manner with medium to good regioselectivity, whereas the parent allyloxy lithium 4 undergoes complete 1,2-addition. The results from DFT calculations of HMPA...

An efficient and operationally simple synthesis of fluoroalkanes by deoxygenative hydrofluorination of carbonyl compounds via their tosylhydrazone surrogates is reported. The reaction can be carried out in a one-pot procedure directly from carbonyl compounds.

We present a methodology for solving the inverse-quantitative structure-activity relationship (QSAR) problem using the molecular descriptor called signature. This methodology is detailed in four parts. First, we create a QSAR equation that correlates the occurrence of a signature to the activity values using a stepwise multilinear regression technique. Second, we construct constraint equations,...

Recent advances in the palladium-catalyzed remote functionalization of carbonyl derivatives are highlighted in this review. The structure of the article is based on the three strategies that have emerged in recent years as the most viable tactics to construct C(sp(3))-C, C(sp(3))-N or C(sp(3))-O bonds at a distance of at least three carbon atoms from the carbonyl functionality. The specific asp...