The nucleation of a droplet of stable cylinder phase from a metastable lamellar phase is examined within the single-mode approximation to the mean-field Landau–Brazovskii model for diblock copolymer melts. By employing a variational ansatz for the droplet interfacial profile, an analytic expression for the interfacial free energy of an interface of arbitrary orientation between cylinders and la...

The relatively simple Ohta-Kawasaki density functional theory for diblock copolymer melts allows us to construct and analyze exact solutions to the EulerLagrange equation by singular perturbation techniques. First we consider a solution of a single sphere pattern that models a cell in the spherical morphology. We show the existence of the sphere pattern and find a stability threshold, so that i...

Title of Thesis: MODELING OF INTERFACES: APPLICATIONS IN SURFACE AND POLYMER PHYSICS Paul Patrone, Doctor of Philosophy, 2013 Dissertation directed by: Professor Theodore L. Einstein Department of Physics In this dissertation, I give an overview of my work on multiscale modeling of interfaces in crystalline and block-copolymer systems. I focus on two distinct interface systems: steps on vicinal...

We measured oxygen isotope compositions of 34 adakites, high-Mg andesites, and lavas suspected to contain abundant slab and sediment melts from the Western and Central Aleutians, the Andes, Panama, Fiji, Kamchatka, Setouchi (Japan), and the Cascades. This suite covers much of the diversity of arc lavas previously hypothesized to contain abundant dslabT melts. Measured and calculated values of y...

Information on the vaporization processes and thermodynamic properties of glass-forming oxide melts in the systems MgO-B2O3-SiO2, CaO-B2O3-SiO2, SrO-B2O3-SiO2, BaO-B2O3-SiO2, PbO-B2O3-SiO2, CdO-B2O3-SiO2, ZnO-B2O3-SiO2, Bi2O3-B2O3-SiO2 and Bi2O3-GeO2-SiO2 together with the earlier obtained data is discussed. These data were obtained by high-temperature mass spectrometric method. Various types o...

Modern plate tectonic brings down oceanic crust along subduction zones where it either dehydrates or melts. Those hydrous fluids or melts migrate into the overlying mantle wedge trigerring its melting which produces arc magmas and thus additional continental crust. Nowadays, melting seems to be restricted to cases of young (< 50 Ma) subducted plates. Slab melts are silicic and strongly sodic (t...

Deoxyribozymes, or DNAzymes, are DNA molecules with enzymatic activity. DNAzymes with ribonuclease activity have various potential applications in biomedical and bioanalytical fields; however, most constructs have limited turnover despite optimization of reaction conditions and DNAzyme structures. A cationic comb-type copolymer accelerates DNA hybridization and strand exchange rates, and we hyp...

[1] Peridotitic xenoliths in basaltic andesites from Batan island in the Luzon arc contain silica-rich (broadly dacitic) hydrous melt inclusions that were likely trapped when these rocks were within the upper mantle wedge underlying the arc. These melt inclusions have been previously interpreted to be slab-derived melts. We tested this hypothesis by analyzing the oxygen isotope compositions of ...

[1] Knowledge about the properties of silicate melts is needed by volcanologists and petrologists to evaluate the dynamics of volcanic eruptions and magmatic processes. These properties include the solubility and diffusivity of volatile components in silicate melts, silicate melt viscosity, and the fragmentation condition. Data and models of each property are reviewed and assessed. For rhyoliti...

The lattice cluster theory (LCT) for semiflexible linear telechelic melts, developed in Paper I, is applied to examine the influence of chain stiffness on the average degree of self-assembly and the basic thermodynamic properties of linear telechelic polymer melts. Our calculations imply that chain stiffness promotes self-assembly of linear telechelic polymer melts that assemble on cooling when...