Monodisperse cobalt nanoparticles are synthesized via a high-temperature thermal decomposition method in the presence of oleic acid and triphenylphosphine. The as-synthesized nanoparticles are stable against further deep oxidation when they are kept in heptane .C7H16/. Time-dependent XPS studies indicate that oxidation of the as-synthesized cobalt nanoparticles in air is slow. The valence chang...

MOTIVATION A tool that simultaneously aligns multiple protein sequences, automatically utilizes information about protein domains, and has a good compromise between speed and accuracy will have practical advantages over current tools. RESULTS We describe COBALT, a constraint based alignment tool that implements a general framework for multiple alignment of protein sequences. COBALT finds a co...

Hypersensitivity reactions in patients receiving metal-on-metal hip replacements have been attributed to corrosion products as observed by elevated cobalt and chromium ions in the blood. Although the majority of cases are reported in metal-on-metal, incidences of these reactions have been reported in the metal-on-polyethylene patient population. To date, no in vitro study has considered cobalt ...

The Costa Rica upwelling dome (CRD; ;8.678N and 90.68W) was characterized chemically for cobalt and nickel abundances and speciation and biologically using cyanobacterial abundances and phylogeny. Total dissolved cobalt was 93 pmol L21 at 90 m depth and decreased in surface waters to 45 pmol L21 at 10 m. Cobalt was 40% labile at 90 m but was completely complexed by strong ligands at 10 m. A sur...

F ROM time to time during the past several years, reports have filtered into the College of an unhealthy condition of cattle in the northern counties of New York State which clearly could not be diagnosed as de, ficiencies of phosphorus, calcium or a lack of total feed. As information concerning cobalt deficiency became more abundant, many points of similarity were recognized batween the sympto...

Films of brucite-type cobalt hydroxide with nanorod morphology and hydrotalcite-type cobalt hydroxide with nanosheet morphology films were fabricated by heterogeneous nucleation in a chemical bath using water and a mixed solution of water–methanol as solvents, respectively. Since oxygen is around 25 times more soluble in methanol than in water, a methanol solution was used to convert a part of ...

Scanning electron microscopy, linear sweep voltammetry, chronoamperometry, and in situ surface-enhanced Raman spectroscopy were used to investigate the electrochemical oxygen evolution reaction (OER) occurring on cobalt oxide films deposited on Au and other metal substrates. All experiments were carried out in 0.1 M KOH. A remarkable finding is that the turnover frequency for the OER exhibited ...

OBJECTIVE To integrate recent understandings of the mechanisms of genotoxicity and carcinogenicity of the different cobalt compounds. METHOD A narrative review of the studies published since the last IARC assessment in 1991 (genotoxicity, experimental carcinogenesis, and epidemiology). RESULTS Two different mechanisms of genotoxicity, DNA breakage induced by cobalt metal and especially hard...

The peculiar characteristics of dust toxicity are discussed in relation to the processes taking place at the particle-biological medium interface. Because of surface reactivity, toxicity of solids is not merely predictable from chemical composition and molecular structure, as with water soluble compounds. With particles having the same bulk composition, micromorphology (the thermal and mechanic...

Processing of self-assembled magnetic nanocrystals has vitally scientific and technological interests. In this paper, three different kinds of self-assemblies of cobalt nanocrystals were processed using particles processed by thermal decomposition of cobalt carbonyl in toluene. In case 1, two-dimensional self-assembly of cobalt nanocrystals with an average particle size of 9.2 nm and polydisper...