A channel-equipped metal-organic framework (1-pyr), resulting from the pyrolysis of [(CH3)2NH2]@[Eu2L3(HCOO)] (1) (L(2-) = isophthalate), showed the preferable absorption of CO2 and the Eu(III)-based emission quenched by aromatics.

Separation is one of the most important process in all the chemical industries and the gas absorption is the simplest example of separation process which is generally used for the absorption of dilute components from a gaseous mixture. In the present work, a dynamic system of mathematical equation (algebraic and differential) is modeled to predict the behavior of the absorption column using mat...

Enhancing carbon sequestration in soil is an important means to reduce net emissions of carbon dioxide (CO2) to the atmosphere. The soil organic carbon (SOC) pool is the net result of carbon (C) input in the form of crop residue and biomass, and output including CO2 ̄ux and other losses. The objectives of this study were to: (1) determine the in ̄uence of known additions of crop residue in a no ...

Owing to the stringent environmental legislations, CO2 capture and sequestration is one of the viable solutions to reduce the CO2 emissions from various sources. In this context, Ionic liquids (ILs) are being investigated as suitable absorption media for CO2 capture. Due to their non-evaporative, non-toxic, and non-corrosive nature, these ILs have the potential to replace the existing solvents ...

Absorption of anthropogenic carbon dioxide by the world’s oceans is causing mankind’s ‘other CO2 problem’, ocean acidification1. Although this process will challenge marine organisms that synthesize calcareous exoskeletons or shells2–6, it is unclear how it will affect internally calcifying organisms, such as marine fish7. Adult fish tolerate short-term exposures toCO2 levels that exceed those ...

In a previous series of papers, a model for the calculation of CO2-air absorption coefficients taking line-mixing into account and the corresponding database/software package were described and widely tested. In this study, we present an update of this package, based on the 2008 version of HITRAN, the latest currently available. The spectroscopic data for the seven most-abundant isotopologues a...

Emissions from strong point sources, primarily large power plants, are a major portion of the total CO2 emissions. International climate agreements will increasingly require their independent monitoring. A satellite-based, double-pulse, direct detection Integrated Path Differential Absorption (IPDA) Lidar with the capability to actively target point sources has the potential to usefully complem...

Mononethanolamine (MEA)-based absorption-stripping for CO2 capture is studied. Energy demands in this process are dominated by the stripping column. The shortest stripping line distance approach is used to determine minimum energy requirements for the MEA stripping column under various lean loadings. Simultaneous reaction and vapor-liquid equilibrium is assumed and modeled by the direct incorpo...

We develop a new 1D photochemical kinetics code to address stratospheric chemistry and stratospheric heating in hot Jupiters. Here we address optically active S-containing species and CO2 at 1200 ≤ T ≤ 2000 K. HS (mercapto) and S2 are highly reactive species that are generated photochemically and thermochemically from H2S with peak abundances between 1-10 mbar. S2 absorbs UV between 240 and 340...