Dihydroxyacetone phosphate was prepared in 2OGmmol scale from dihydroxyacetone by two procedures: reaction with phosphorus oxytrichloride and glycerol kinase catalyzed phosphorylation using ATP with in situ regeneration of ATP by phosphoenolp5rruvate or acetyl phosphate. Dihydroxyacetone phosphate was converted to fructose 6-phosphate in 80% yield by exposure to a mixture of co-immobilized trio...

Propylamino-functionalized mesoporous thin films were synthesized via co-condensation of the oxide precursor tetraethoxysilane (TEOS, Merck) and the amine precursor 3-aminopropyltriethoxysilane (APTES, Fluka 98%) in the presence of the template (F127 block copolymer, Aldrich, Mw ~13600). The precursor solution was prepared using 0.8 TEOS:0.2 APTES:0.005 F127:24 EtOH:5.2 H2O:0.28 HCl. This solut...

Inelastic cold-neutron scattering on LaCoO3 provided evidence for a distinct low energy excitation at 0.6 meV coincident with the thermally induced magnetic transition. Coexisting strong ferromagnetic (FM) and weaker antiferromagnetic correlations that are dynamic follow the activation to the excited state, identified as the intermediate S = 1 spin triplet. This is indicative of dynamical orbit...

The side product of the cyclo-condensation reaction between ethyl benzimidazole-2-carboxyl-ate and the nitrile imine of the corresponding hydrazonyl chloride, C20H11BrClN5O, crystallized in two crystal forms. Form (1) is a co-crystal of the target compound (without any chlorine substituent) and a side product containing a Cl atom in position 2 of the bromo-phenyl group, C20H12BrN5O·0.143C20H11B...

Large colloidal environmentally stable silica-coated cobalt particles were synthesized by combining the sodium borohydride reduction in aqueous solution and the Stöber method. Low size polydisperse cobalt spheres with an average size of 95 nm were synthesized by using a borohydride reduction method and were subsequently coated with a thin layer of silica by means of hydrolysis and condensation ...

The oxidation of naphthalene by immobilized laccase from Trametes versicolor has been performed using diverse immobilization strategies on mesostructured silica materials. Laccase was immobilized by physical adsorption on several SBA-15 with different textural properties and by covalent attachment on functionalized SBA-15 prepared by co-condensation method (direct synthesis). The adsorption of ...

It was argued in \cite{DallAgata:2022abm} that the Volkov-Akulov (VA) model as well similar models supergravity and related KKLT string theory, suffer from tachyonic instabilities due to goldstino condensation. The authors of constructed a specific with two unconstrained interacting chiral superfields linearly realized supersymmetry which has an unstable vacuum. They claimed this becomes equiva...

A bishydrazone was obtained by the condensation of isatin monohydrazone with 2hydroxyquinoline-3-carbaldehyde, which formed a series of complexes with Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II). The ligand and its metal complexes were characterized on the basis of elemental analysis, conductance data, magnetic susceptibility measurements, IR, UV-Vis, mass, H NMR, ESR and XRD studies. By ...

the silver spr chip was modified by alkaline-silane condensation with aminopropyltriethoxysilane (aptes) in naoh aqueous solution at different times. silver sputtered slides coated with aptes were immersed in naoh solution, enabling us to produce silver surfaces homogeneously covered with aptes. the surface properties of grafted aptes on sputtered silver surface as a occasion of time were studi...