we introduce a model for prediction the behavior of electrodes which modified withcarbon nanotubes in a polymer medium. these kinds of polymer composites aredeveloped in recent years, and experimental data for its percolation threshold isavailable. we construct a model based on percolation theory and fractal dimensionsand using experimental percolation threshold for calculating the moments of c...

Novel boron dipyrromethene (BODIPY) derivatives having significant absorption and emission in the longer wavelength region were synthesized. BODIPY showed anomalous S(2) emission from the second excited (S(2)) state at shorter wavelength. The photodynamics of the S(2) state was investigated by fluorescence up-conversion and transient absorption spectroscopic measurements. The decay time of the ...

Silicon and graphene are promising anode materials for lithium-ion batteries because of their high theoretical capacity; however, low volumetric energy density, poor efficiency and instability in high loading electrodes limit their practical application. Here we report a large area (approximately 15 cm × 2.5 cm) self-standing anode material consisting of molecular precursor-derived silicon oxyc...

A mathematical model describing the transport and kinetics of substrate and redox mediator in surface deposited films of finite thickness is described. These bio-catalytically active chemically modified electrodes comprise redox enzymes immobilized in a highly dispersed mesh of single walled carbon nanotubes (SWNT) which are in turn immobilized on a support metal surface. A small molecule redox...

An efficient active material for supercapacitor electrodes is prepared by reacting potassium hydroxide (KOH) with graphene oxide followed by chemical reduction with hydrazine. The electrochemical performance of KOH treated graphene oxide reduced for 24 h (reduced chemically modified graphene oxide, RCMGO-24) exhibits a specific capacitance of 253 F g(-1) at 0.2 A g(-1) in 2 M H2SO4 compared to ...

We report on the construction and magnetic characterization of a fully functional hybrid molecular system composed of a single magnetic porphyrin molecule bonded to graphene nanoribbons with atomically precise contacts. We use on-surface synthesis to direct the hybrid creation by combining two molecular precursors on a gold surface. High-resolution imaging with a scanning tunneling microscope f...

A mathematical model describing transport and kinetics of substrate and redox mediator within chemically modified electrodes comprising of redox enzymes immobilized in dispersed carbon nanotube meshes dispersed on support electrode surfaces is described. Two modes of amperometric detection are subjected to analysis. In the first the current arising from re-oxidation of the reduced mediator at t...

A potentiometric enzyme biosensor is a convenient detector for quantification of urea concentrations in industrial processes, or for monitoring patients with diabetes, kidney damage or liver malfunction. In this work, poly(3-hexylthiophene-co-3-thiopheneacetic acid) (P(3HT-co-3TAA)) was chemically synthesized, characterized and spin-coated onto conductive indium tin oxide (ITO) glass electrodes...

We introduce a high-performance molecular sensor using self-corrugated chemically modified graphene as a three dimensional (3D) structure that indicates anisotropic charge distribution. This is capable of room-temperature operation, and, in particular, exhibiting high sensitivity and reversible fast response with equilibrium region. The morphology consists of periodic, "cratered" arrays that ca...