Size dependent stabilities, fragmentation pathways and dissociation energies of a series of gas phase cationic doped gold clusters, Au(n)X+ (3 < or = n < or = 20; X = Y, Er and Nb), and pure Au(n)+ clusters were investigated in photofragmentation experiments. Size dependent stability patterns were obtained and the branching between monomer and dimer evaporation was studied. For bare gold, the c...

Gas-to-PVC In their Research Article on page 24162, Guido Zichittella and Javier Pérez-Ramírez show the outstanding performance of rare earth oxychloride catalysts for selective conversion ethane into 1,2-dichloroethane, a precursor vinyl chloride monomer. The potential use natural gas as feedstock instead coal or oil represents long sought-after advancement to bring significant cost environmen...

background: acrylamide (c3h5no) is a vinyl monomer. this water-soluble crystalline solid is a colorless, odorless agent which is used in scientific laboratories and some industries. acrylamide has cellular oxidative effects. acute or chronic poisoning with this agent happens as a result of skin, respiratory, or oral contacts. clinical manifestations depend on the dose, duration, and frequency o...

This work demonstrates the synthesis of core-shell ZrO2/PAAEM/PS nanoparticles through a combination of sol-gel method and emulsifier-free emulsion polymerizaiton. By this method, the modified nanometer ZrO2cores were prepared by chemical modification at a molecular level of zirconium propoxide with monomer of acetoacetoxyethylmethacrylate (AAEM), and then copolymerized with vinyl monomer to fo...

Flexible and transparent gas-diffusion barriers have played an important role in recent years. The present study describes a flexible barrier film with a tailored architecture of cationic polyelectrolytes and clay/polymer nanoassemblies. Highly oriented and well-aligned barrier films were achieved by the consecutive absorption of flexible cationic polymer and anionic montmorillonite platelets. ...