simultaneous thermal analysis (sta) method has been applied to study decomposition reactions of ap under a flowing nitrogen atmosphere and static air. results obtained indicate that a phase transformation occurs prior to the decomposition reaction. decomposition takes place exothermally in two stages, first stage of decomposition could be suppressed by the controlled heating programme. addition...

a series of x(co, mn)/tio2 catalysts (x=2–12wt.%) containing 25%co and 75%mn were prepared by the co-impregnation method. all prepared catalysts have been tested in fischer-tropsch synthesis for production of c2-c4 olefins. it was found that the catalyst containing 8wt.%(co,mn)/tio2 is an optimal catalyst for production of c2-c4 olefins. the effect of operation conditions such as the h2/co mola...

waste low density polyethylenes (ldpe) represent a source of energy and valuablechemicals, were pyrolysed catalytically in a batch reactor under atmospheric pressure. calciumcarbide was used as a catalyst to explore its effect on pyrolysis product distribution. the effect oftemperature, amount of catalyst and time on the yields of the pyrolysed products wasinvestigated. the effect of catalyst o...

with its well-known biological toxicity, the excessive concentrations of sulfide in tannery wastewaters may upset the biological treatment processes, thus leading to a substantial decrease in the efficiency of treatment plants. the presence of sulfide in wastewaters may dramatically interfere with microbial activities and consequently disturb the function of the system as a whole. in this study...

Background: Deoxyribozymes (Dzs) can play a role as gene expression inhibitors at mRNA level. Among Dzs, the 10-23 deoxyribozyme has significant potentials for treatment of diseases. Designed Dz includes a catalytic core made of 15 deoxyribonucleotides and two binding arms consisted of 6-12 nucleotides for site specific binding to target RNA and hydrolysis. The enzyme has characteristic feature...

treatment of asthma. Compound B (NPS 1392) is a potent stereoselective antagonist of the NMDA receptor, which can be used for the control of ischemic strokes. To our knowledge, there has been no successful catalytic method to make such important functional groups. Although some stoichiometric asymmetric synthesis or resolution routes have been reported for constructing this class of chiral amin...

Kinetics of model catalytic processes proceeding on inhomogeneous surfaces is studied. We employ an extended mean-field model that takes into account surface inhomogeneities. The influence of surface diffusion of adsorbent on the kinetics of the catalytic process is investigated. It is shown that diffusion is responsible for differences in the reaction rate of systems with different arrangement...

An azadithiolate bridged monocyanide derivative [Fe2(adt)(CO)5(CN)]- of [Fe2(adt)(CO)4(CN)2]2- has been prepared and extensively characterized as a model of the [FeFe]-hydrogenase active site, using a combination of FTIR spectroscopy, electrochemical methods and catalytic assays with chemical reductants. The presence of two basic nitrogen sites opens up multiple protonation pathways, enabling c...

the most accurate method for calculating the aeroheating is numerical solution method. using finite volume method to solve the navier-stokes equations in time is very time consuming. so by using the finite difference algorithm, transfer equations to curvature coordinate by the mapping function, and combination of the viscous shock layer and similarity of boundary layer, the ctca code was develo...