Abstraet--Jordanian natural kaolin and bentonite show good catalytic activity towards debutylating 2tert-butylphenol, and varying debutylation vs. isomerization selectivity after acid activation. The resulting catalytic activity of these samples is dependent on the acid employed for activation; the samples treated with acetic acid showed relatively low conversions, whereas those treated with hy...

The selective hydrogenation of dimedone (1) to the corresponding monoketone 2 over palladium and Amberlyst 15 ® is reported. The product is a synthetic building block for the fragrance and pharmaceutical industry. Advantages of the new catalytic procedure are the high catalyst activity and selectivity, less by-product formation, avoidance of the presence of acid, and consequently, less salt for...

The effect of transition metal doping on Pt/Al2O3 catalyst used in propane dehydrogenation reaction at 500 ̊C was studied. The preparation methods investigated were sequential impregnation (Pt followed by the 2 metal or the 2 metal followed by Pt) and co-impregnation. The metal contents of these catalysts were fixed as the weight ratio of Pt per the 2 metal of around 0.075. These catalysts were ...

This paper presents the performance studies of ATM via satellite based on experiments implemented by the RACE II CATALYST project R2074. The purpose of the project was to develop an ATM satellite link for the future B-ISDN services, particularly for the interconnections of the ATM testbeds which are in the form of broadband islands. Then initial ATM based B-ISDN can be introduced by interconnec...

This study aims to examine the operating pressure effect on manufacture of biodiesel from Palm Kernel Fatty Acid Distillate (PKFAD) by using para-Toluene Sulfonic (PTSA) catalyst. The pressures studied are vacuum 70 kPa, 80 90 and 100 which varied with PTSA concentrations 5%, 10%, 15%, 20%, 25%, molar ratios methanol PKFAD 5:1, 6:1, 7:1, 8:1, 9:1, 10:1. Biodiesel production is carried out react...

palladium is the best metal catalyst for suzuki cross coupling reaction for synthesize of unsymmetrical biaryl compounds. but its high cost limits its application in wide scale. using of nanoscale particles as active catalytic cites is a good approach for reducing needed noble metal. by loading precious nanoparticles on magnetic nanocores as a support, recycling and reusing of catalyst will be ...

The Pd(OAc)(2)/pyridine catalyst system is one of the most convenient and versatile catalyst systems for selective aerobic oxidation of organic substrates. This report describes the catalytic mechanism of Pd(OAc)(2)/pyridine-mediated oxidation of benzyl alcohol, which has been studied by gas-uptake kinetic methods and (1)H NMR spectroscopy. The data reveal that turnover-limiting substrate oxida...

The CO sensing properties of a micro thermoelectric gas sensor (micro-TGS) with a double AuPtPd/SnO₂ and Pt/α-Al₂O₃ catalyst were investigated. While several nanometer sized Pt and Pd particles were uniformly dispersed on SnO₂, the Au particles were aggregated as particles measuring >10 nm in diameter. In situ diffuse reflectance Fourier transform Infrared spectroscopy (DRIFT) analysis of the c...

Concentrated livestock feeding operations have become a source of odorous gas emissions that impact air quality. Comprehensive and practical technologies are needed for a sustainable mitigation of the emissions. In this study, we advance the concept of using a catalyst for barn walls and ceilings for odor mitigation. Two catalysts, a new TiO2-based catalyst, PureTi Clean, and a conventional Evo...