in this study, a novel solid dendrimer amine (hyperbranched polymers) was prepared using mesoporous carbon nitride functionalized by melamine based dendrimer amines. this adsorbent was denoted mda-mcn-1. the process was stepwise synthesis and hard-templating method using mesoporous silica sba-15 as a template. cyanuric chloride and n,n-diisopropylethylamine (dipea, merck) were used for function...

The Greta oto butterfly has transparent wings with extraordinary omnidirectional anti-reflection behavior, owing to unusual nanostructures random height and pitch/space distribution on its wing surface. beauty efficacy of such are proven designs but difficult reproduce en masse. Here, we establish a low-cost bottom-up approach by simply stacking monolayer-aligned agitation-assisted deposition s...

Platinum (Pt) nanopetals were electrodeposited on highly ordered silicon nanocones (SiNCs) and explored as the electrocatalyst for methanol oxidation reaction (MOR) for direct methanol fuel cells applications. Highly ordered SiNCs array fabricated using the porous anodic aluminum oxide as the template had a high surface area. Well-dispersed Pt nanopetals possessing high electrocatalytic surface...

Here, we have synthesized Ag2O3-ZnO nanocones (NCs) by a wet-chemical route using reducing agents at low temperature. The structural, optical and morphological properties of Ag2O3-ZnO NCs were investigated by several conventional techniques such as powder XRD, XPS, FESEM, XEDS, FTIR and UV/vis. spectroscopy. The analytical parameters of prepared NCs were also calculated for a selective detectio...

carbon dioxide is a major greenhouse gas that contributes to the global warming by more than %60. absorption has been widely used to treat high concentrations of co2 in synthesis gas production, hydrogen manufacturing, and natural gas processing. the most well established method to capture co2 is its removal by absorption into amine solutions in the presence of activators. in this research, co2...

The slow kinetics of oxygen evolution reaction (OER) causes high power consumption for electrochemical water splitting. Various strategies have been attempted to accelerate the OER rate, but there are few studies on regulating transport reactants especially under large current densities when mass transfer factor dominates reactions. Herein, NixFe1–x alloy nanocones arrays (with ?2 nm surface Ni...

Metal-assisted chemical etching (MaCE) of a (100) n-type GaP using patterned Pd catalysts in a mixed solution of HF and H2O2 at room temperature is reported for the first time. Various patterns of Pd catalysts, i.e., meshes and patches, with length scales ranging from 200 nm to several μm were used. Depending on the sizes of the Pd catalysts, GaP exhibits two distinctively different MaCE mechan...

Bachelor of Science in Electrical Engineering and Computer Science and Bachelor of Science in Physics Massachusetts Institute of Technology (2011) Submitted to the Department of Electrical Engineering and Computer Science in Partial Fulfillment of the Requirements for the Degree of Master of Engineering in Electrical Engineering and Computer Science at the MASSACHUSETTS INSTITUTE OF TECHNOLOGY ...

in the present study, carbon species including organic carbon (oc), elemental carbon (ec), and water-soluble organic carbon (wsoc) concentration in pm2.5 were assessed at an urban site of tehran, iran during march to june 2014. the pm2.5 samples were collected using an frmomnitm ambient air sampler. thermal gravimetric analysis (tga) was used to analyze oc and ec. the results showed that pm2.5 ...