The present study developed a facile and fast electrochemical approach to sensitively analyze Sudan I using Fe3O4-ZIF-67 nanocomposite plus ionic liquid (IL). carbon paste electrode (CPE) modified with Fe3O4-ZIF-67/IL exhibited an excellent sensing performance I. Compared the unmodified CPE, Fe3O4-ZIF-67/ILCPE could significantly increase peak current of oxidation decrease overpotentials. Under...

Solvent free ionic liquid (IL) electrolytes facilitate high-voltage supercapacitors with enhanced energy density, but their complex ion arrangement and through that the electrochemical properties, are limited by strong Coulombic ordering in bulk state like-charged repulsion at electrified interfaces. Herein, a unique interfacial phenomenon resulting from presence of carbon dioxide loaded 1-Ethy...

A single-use electrochemical sensor using ionic liquid mediated hollow fiber-graphite working electrode was fabricated for the first time. The screening tool was developed by coupling this electrode with differential pulse voltammetry (DPV) for in-situ pre-concentration and determination of Zn(II) and Cu(II). In our plot, porous polypropylene hollow fiber membrane divided into pieces of 2 cm, t...

a direct and an efficient conversion of a wide range of primary, secondary even tertiary alcohols to the corresponding iodides have been achieved under ionic liquid conditions. the method involves preparation of ionic liquid-based iminium chloride intermediate from dmf-like ionic liquid then stirring it with alcohol in present of sodium iodide. the higher yields of alkyl iodides were obtained w...

Fast and sensitive response electrochemical sensor based on CoFe2O4 nanoparticle and 1-buthyl-3-methyl imidazolium bromide room temperature ionic liquids carbon paste electrode (CoFe2O4/NP/ILs/CPE) is fabricated for the determination of Xanthine (Xt) in the presences of Caffeine in fish and fruit samples. In the first step, CoFe2O4</su...

Addressed herein, functionalized multi-walled carbon nanotube (MWCNT) supported highly monodisperse nickel nanoparticles modified on glassy carbon electrode (Ni@f-MWCNT/GCE) were synthesized through microwave assisted method and examined for non-enzymatic glucose sensing in ionic liquids by cyclic voltammetry and chronoamperometry. The results of Ni@f-MWCNT/GCE electrode were compared with Ni N...

A liquid membrane disk electrode, LMDE, and a liquid membrane ring-liquid membrane disk electrode, LMRE-LMDE, were developed by placing a gelled polyvinyl chloride thin membrane impregnated with 2-nitrophenyl octyl ether, NPOE-LM, on the surface of a glassy carbon, GC, disk or ring electrode. The voltammogram for the ion transfer at the interface between an aqueous solution, W, and NPOE-LM was ...

The electrochemical behavior of cobaltocenium has been studied in a number of room temperature aprotic ionic liquids. Well defined, diffusion controlled, anodic and cathodic peaks were found for the Cc+/Cc (cobaltocenium/cobaltocene) reduction/oxidation on gold, platinum and glassy carbon electrodes. Values of the peak separation parameters suggest quasireversibility or even irreversibility for...

The direct CO2 electrochemical reduction on model platinum single crystal electrodes Pt(hkl) is studied in [C2mim(+)][NTf2(-)], a suitable room temperature ionic liquid (RTIL) medium due to its moderate viscosity, high CO2 solubility and conductivity. Single crystal electrodes represent the most convenient type of surface structured electrodes for studying the impact of RTIL ion adsorption on r...

Room temperature ionic liquids (RTILs) are an emerging class of electrolytes enabling high cell voltages and, in return, high energy density of advanced supercapacitors. Yet, the low temperature behavior, including freezing and thawing, is little understood when ions are confined in the narrow space of nanopores. This study shows that RTILs may show a tremendously different thermal behavior whe...