The methanol-to-olefin (MTO) process allows the conversion of methanol/dimethyl ether into olefins on acidic zeolites via the so-called hydrocarbon pool mechanism. However, the site and mechanism of formation of the first carbon-carbon bond are still a matter of debate. Here, we show that the Lewis acidic Al sites on the 110 facet of γ-Al2O3 can readily activate dimethyl ether to yield CH4, alk...

Redox reaction [Fe(CN)6] 3– / [Fe(CN)6] 4– has been studied with a Single-Walled Carbon Nanotube (SWCNT)-coated Glassy Carbon Electrode (GCE), SWCNT-coated Gold Electrode (GE) and a lab-made SWCNT-TPLF (SWCNT-Thin-Paper-Like-Film) Electrode. The SWCNT-modified electrode has shown a well-defined redox peak compared to bare electrodes. Cyclic voltammetry was used in 50.0 × 10–3 M aqueous solution...

Preparation of carbon coated FeWO4 was carried out by heat treatment of WO2.9 with iron acetate at 400 o C, followed by carbonization with poly(vinyl alcohol) (PVA) as carbon precursor at 800 o C in N2 atmosphere. The powders mainly consist of FeWO4. The photocatalytic activities of their samples were confirmed by phenol photodecomposition in its aqueous solution. Carbon coated FeWO4 powders re...

A precise control of the dimension of carbon nanotubes (CNTs) in their vertical array could enable many promising applications in various fields. Here, we demonstrate the growth of vertically aligned, single-walled CNTs (VA-SWCNTs) with diameters in the sub-1.5-nm range (0.98 ± 0.24 nm), by engineering a catalyst support layer of alumina via thermal annealing followed by ion beam treatment. We ...

We revised seven alumina-blasted cementless hip prostheses (Ti-alloy stems, cp Ti threaded sockets) with low- or high-carbon Co-alloy bearings at a mean of 20.1 months after implantation because of pain and loosening. Histological examination of the retrieved periprosthetic tissues from two cases in which the implant was stable and three in which the socket was loose showed macrophages with bas...

Citation: Castro-Muñiz A, Hoshikawa Y, Komiyama H, Nakayama W, Itoh T and Kyotani T (2016) Improving the Direct Electron Transfer in Monolithic Bioelectrodes Prepared by Immobilization of FDH Enzyme on Carbon-Coated Anodic Aluminum Oxide Films. Front. Mater. 3:7. doi: 10.3389/fmats.2016.00007 improving the Direct electron Transfer in Monolithic Bioelectrodes Prepared by immobilization of FDh en...

In this study, polymer composite membranes comprising carbon nanotube (CNT), polysulfone (PSF) and polyvinyl alcohol (PVA) were synthesized via the phase inversion method and used to remove phenol from the phenol-containing wastewater. The fabricated membranes were reinforced with the functionalized carbon nanotubes (fCNTs) and coated with PVA to enhance their mechanical strength and anti-fouli...