The synthesis, characterization, and charge transport performance of novel copolymers PNDIFu2 made from alternating naphthalene diimide (NDI) and bifuran (Fu2) units are reported. Usage of potentially biomass-derived Fu2 as alternating repeat unit enables flattened polymer backbones due to reduced steric interactions between the imide oxygens and Fu2 units, as seen by density functional theory ...

A series of tetrahedral oligothiophenes bearing n-hexyl groups at the α-positions of the terminal thiophene rings, (n-C(6)H(13)(C(4)H(2)S)(n))(4)C (Hex-TnTM; n=1-4), has been synthesized by Kosugi-Migita-Stille coupling as a key reaction. Thanks to the improved solubility afforded by the terminal n-hexyl groups, the largest homologue (n=4) was successfully obtained. Whereas the smaller derivati...

Studies on structural characterisation and anion binding properties of a series of core modified meso-aryl sapphyrins and rubyrins are described. It has been shown that the sapphyrins and rubyrins bind anions such as F , N3 and CO3 2 in their protonated form. The binding constants evaluated for a particular sapphyrin vary in the order F ≅ N3 < CO3 and this has been accounted for in terms of com...

Poly(3-alkylthiophene) is a family of conjugated semicrystalline polymers for organic electronic applications. Crucial for the fine-tuning of such systems is a detailed understanding of the correlation between molecular structure/morphology and electronic properties. However, a series of a priori assumptions is commonly made in order to deduce macromolecular-scale geometric and energetic featur...

The synthesis of key 4-alkyl-substituted 5-(trimethylsilyl)thiophene-2-boronic acid pinacol esters 3 allowed a simplified alkylthiophene catenation process to access bis-, ter-, quater-, and quinquethiophene π-bridges for the synthesis of acceptor-π-bridge-donor- π-bridge-acceptor (A-π-D-π-A) electron donor molecules. Based on the known benzodithiophene-terthiophene-rhodanine (BTR) material, th...

Chemosensing systems were devised for the enantioselective determination of Dand L-phenylalanine (Dand L-Phe). As recognition units of these systems, molecularly imprinted polymers (MIPs) were designed, guided by DFT calculations, and then synthesized. For the preparation of these MIPs, carboxy derivatized bis(bithiophene) was used as the functional monomer. Both templated and templateextracted...

New building units (unimers) for metallo-supramolecular polymers 2,5-bis(2,2':6',2''-terpyridine-4'-yl)thiophene, M, and 5,5'-bis(2,2':6',2''-terpyridine-4'-yl)(2,2'-bithiophene), B, with ionic groups attached to thiophene rings are prepared by the modification of corresponding bromo-precursors and assembled with Zn(2+) and Fe(2+) ions into alcohol-soluble conjugated constitutional-dynamic poly...

2,2’-Bithiophene-5-carboxylic acid (BTA) thin-films on platinum (Pt) electrodes were electrochemically prepared in acetonitrile solution containing 0.1 M tetrabutylammonium perchlorate (TBAP) and 0.05 M BTA. These films were complexes with several metal ions such as Cu, Ag and Co. Their structural characteristics were compared with those of powder complexes chemically prepared from BTA and the ...