Binuclear dithiocarbamate complexes of Ru(III) are promising candidates in the search for outstanding metal-based anticancer agents. While different dithiocarbamates have shown ligand-dependent cytotoxicity homoleptic binuclear complexes, properties heteroleptic analogues with (DTC) ligands yet to be explored. We herein propose introduction as tunable features development improved ruthenium-bas...

The cation Hgz2+ may be regarded as the simplest binuclear complex that contains a metal-metal single bond. This bond consists of an electron pair in a ubonding MO which is formed by the interaction of the 6s orbitals of both mercury ions [ 11. While in numerous studies it has been shown that metal-metal single bonds of binuclear transition metal complexes can be split homolytically by uu* exci...

In the present study we have synthesized new binuclear complexes of alkali and alkaline earth metal salts with interaction of stable metal chelates of isonitrosopropiophenone of Ni(II) & Cu(II) having general formula [Ma(INPP)2.MbL] and [Ma(INPP)2.MbX] for alkali metal adducts and [ Ma(INPP)2.MbL2] and [ Ma(INPP)2.MbX2] for alkaline earth metal adducts where Ma=Ni (II) or Cu(II) and Mb =Li+ , N...