a general and rapid procedure is developed for the selective tritylation of the 'primary oh-function of the four common ribonucleosides, ascorbic acid, and polyhydric compounds. silver ion was found to have a marked effect on tritylation reactions

Molecular simulations have been used to investigate at the molecular level the suitability of zeolites with different topology on the adsorption, diffusion and separation of a nitrogen-sulfur hexafluoride mixture containing the latter at low concentration. This mixture represents the best alternative for the sulfur hexafluoride in industry since it reduces the use of this powerful greenhouse ga...

Despite the sustained use of forcefield methodologies to study SiO(2) polymorphs few reviews on the subject are available in the literature. The present study is an attempt to help fill this gap, focusing on classical forcefields used to reproduce and predict properties of pure silica zeolites (or zeosils) such as cell parameters, SiO distance and especially pore size. Instead of an exhaustive ...

background and aim(s): since it is possible for carbamide peroxide (cp) bleaching agent to contact with amalgam restorations in the oral cavity, the present in vitro study evaluated the amount of dissolved mercury released from amalgam restorations with various percentages of silver content subsequent to the use of 15% cp. materials and methods: thirty ana 2000 amalgam disks with 43.1% silver c...

The first silver-FOX, silver-ammonia-FOX, and silver-amine-FOX compounds were synthesized by the reactions of silver nitrate with K-FOX or guanidine-FOX in water, aqueous ammonia, and amines, respectively. The crystal structure of silver-ammonia-FOX exhibits unique covalent bonding behavior, which is supported by NBO calculations.

Site restoration activities at DOE facilities and the permanent disposal of nuclear waste inevitably involve understanding the behavior of materials in a radiation field. Radionuclide decay and the associated radiation fields lead to physical and chemical changes that can degrade or enhance important material properties. Alpha-decay of the actinide elements and beta-decay of the fission product...

results the results revealed the formation of spherical silver nanoparticles with an average size of 10 nm. moreover, concentration of snps in a 25 ml sample containing both snps and plant extract biomass was 2.934 mg/l on average. serial microdilution test showed that snps at the concentration of 50 μg/ml can inhibit growth of the pathogen. conclusions the present study extends the existing li...

Heterogeneous catalysis and their application in industrial-scale organic synthesis of fine chemicals are greatly facilitated by catalysis and further on by catalyst recovery and recycles to fits most “principles of green chemistry. In acid media, terpenoids generally undergoes various transformations. The terpenoid transformations include various liquid Bronsted and Lewis Acids, Acid clays, He...

Potentiometric sensor based on commercial pencil graphite electrodes coated with polyaniline (PAni) composite with Eosin Y (EY) termed as PGE/PAni-EY have been developed for potentiometric determination of silver ion. The electrode exhibited linear response with Nernstian slope of 57.6±0.8 mV per decade within the range of 1.0×10 to 1.0×10 M with limit of detection 6.5×10 M silver ion. Fast and...