This study investigated perchlorate reduction by sulfur utilizing perchlorate reducing bacteria (SUPeRB). SUPeRB cultures were enriched from a denitrifying wastewater inoculum in medium containing elemental sulfur (S), crushed oyster shell, nutrients and perchlorate. Perchlorate was reduced from 5 to < 0.5 mg/L in approximately 15 days. The enrichment culture was subsequently inoculated into a ...

A novel energetic co-crystal composed of hydrazinium 3-nitro-1,2,4-triazol-5-one (HNTO) and ammonium nitrate (AN), as a composite solid propellant oxidizer, was recently developed to substitute either pure perchlorate (AP) or nitrate. Unfortunately, the thermodynamic properties this even HNTO are not available in open literature. Therefore, work, low-temperature heat capacities HNTO·AN were mea...

A novel environmentally friendly rapid cloud point extraction at room temperature coupled to graphite furnace atomic absorption spectroscopy (RT-CPE-GFAAS) for Copper (II) traces quantification was developed. Were found the most optimal conditions instant surfactant rich phase of Triton X-100 formation and as a complex with 6,7-dihydroxy-2-phenyl-4-methylbenzopyrylium perchlorate (DHMPhB) immed...

The biological degradation of perchlorate was examined using a laboratory-scale, autotrophic, packed-bed biofilm reactor. The reactor was operated in unsaturated-flow mode and continuously fed water containing perchlorate (ClO4-) (as an electron acceptor), and a gas mixture of hydrogen (5%) and carbon dioxide at a retention time of 1.5 min. In the absence of nitrate, perchlorate removal rate (r...

A total of 27 settled dust samples were collected from urban roads, parks, and roofs in Chengdu, China to investigate particle size distribution and perchlorate levels in different size fractions. Briefly, fine particle size fractions (<250 μm) were the dominant composition in the settled dust samples, with mean percentages of 80.2%, 69.5%, and 77.2% for the urban roads, roofs, and the parks, r...

A series of batch experiments were performed to study the combination of zero-valent iron (ZVI) with perchlorate-reducing microorganisms (PRMs) to remove perchlorate from groundwater. In this method, H2 produced during the process of iron corrosion by water is used by PRMs as an electron donor to reduce perchlorate to chloride. Perchlorate degradation rates followed Monod kinetics, with a norma...

Leafy vegetables, such as lettuce ( Lactuca sativa L), have been identified as a potential source of perchlorate exposure to humans. Perchlorate is of concern because excessive amounts may impair thyroid function by inhibiting iodide uptake by the sodium iodide symporter. Perchlorate has been identified as an oxidation product in sodium hypochlorite. Dilute hypochlorite solutions are widely use...

The influence of backwashing on biological perchlorate reduction was evaluated in two laboratory scale fixed bed biofilm reactors using 1- or 3-mm glass beads as support media. Influent perchlorate concentrations were 50 microg/L and acetate was added as the electron donor at a concentration of 2 mg C/L. Perchlorate removal was evaluated at various influent dissolved oxygen (DO) concentrations....

background: considering the controversial information regarding the effects of perchlorate on thyroid function of high risk population as neonates, and given the high prevalence rate of thyroid disorders specially congenital hypothyroidism in our region, this study aims to investigate for the frst time in iran, the relationship between drinking groundwater perchlorate and cord blood thyroid hor...