A crown ether-functionalized poly(tetraphenylethene) (AP-TPE) is synthesized and the rotation of the TPE group is successfully restricted via the complexation of crown ether and organic ammonium salts, leading to a stepwise enhanced fluorescence accompanied by a morphological transition from micellar to vesicular.

Nitrogen-15 ( N)-labeled biogas slurry (digested anaerobic organic residues (DAOR)) and chemical 15 fertilizer (CF) were applied to soil with low fertility cropped with rice. The N dilution method was used to 15 estimate the N uptake and recovery; potted soil was labeled with 1.0 atom % excess [ N] ammonium chloride 15 NH Cl. Certain select soil characteristics were also measured in soil amende...

To assess changes as a result of reduced acidifying deposition, water chemistry data from 68 Dutch moorland pools were collected during the periods 1983-1984 and 2000-2006. Partial recovery was observed: nitrate- and ammonium-N, sulphur and aluminium concentrations decreased, while pH and alkalinity increased. Calcium and magnesium concentrations decreased. These trends were supported by long t...

Friend murine erythroleukemia cells underwent apparently normal erythropoiesis when treated with dimethyl sulfoxide. One of the earliest events associated with this induction was a decrease in ouabain sensitive 86Rb+ uptake, an assay of the plasma membrane Na,K(ATPase). Ammonium vanadate (10 microM) blocked differentiation of these cells without affecting cell viability. Vanadium was taken up b...

A simple microextraction method based on solidification of a floating organic drop (SFOD) was developed for preconcentration of lead prior to its determination by electrothermal atomic absorption spectrometry (ETAAS). Ammonium pyrolidinedithiocarbamate (APDC) was used as complexing agent, and the formed complex was extracted into a 20 μL of 1-undecanol. The extracted complex was diluted with et...

This paper reports on successful laboratory testing of a new nitrogen removal process called DEAMOX (DEnitrifying AMmonium OXidation) for the treatment of strong nitrogenous wastewater such as baker's yeast effluent. The concept of this process combines the recently discovered ANAMMOX (ANaerobic AMMonium OXidation) reaction with autotrophic denitrifying conditions using sulfide as an electron d...

Eight new amido functionalized reagents, L(1)-L(8), have been synthesized containing the sequence of atoms R(2)N-CH(2)-NR'-CO-R″, which upon protonation forms a six-membered chelate with a hydrogen bond between the tertiary ammonium N-H(+) group and the amido oxygen atom. The monocationic ligands, LH(+), extract tetrachloridometal(II)ates from acidic solutions containing high concentrations of ...

The role of mitochondrial phosphoenolpyruvate carboxykinase in both hepatic and renal gluconeogenesis was studied in the chicken since this species reportedly lacks the cytosolic enzyme. Lactate is the major substrate used for glucose synthesis in isolated chicken hepatocytes but pyruvate, glycerol, and some amino acids, as well as lactate, are converted to glucose in isolated chicken kidney tu...

Crystals of lactate dehydrogenase (LDH) were frozen by equilibration in a sucrose-ammonium sulfate solution, and then dipping into liquid nitrogen. The rate of radiation damage for frozen crystals was tenfold less than for crystals at room temperature. The physical properties of frozen crystals are discussed. Analysis of 3"5 A data collected at -75°C for native LDH and two heavy atom derivative...

Aggregation and self-assembly are influenced by molecular interactions. With precise control of molecular interactions, in this study, a wide range of nanostructures ranging from zero-dimensional nanospheres to hierarchical nanoplates and spindles have been successfully synthesized at ambient temperature in aqueous solution. The nanostructures reported here are formed by aggregation of spherica...