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امکان استفاده از پلیمر طبیعی سلولوز به عنوان الیاف طبیعی در کاربردهای صنعتی به دلیل برخی خواص آن از جمله آبدوستی شدید و واکنشپذیری محدود، مشکل است. برای رفع این عیب، سلولوز باید به روش شیمیایی اصلاح شود. از روشهای معمول، پیوندزدن مونومرهای سنتزی به سطح سلولوز و کاهش خاصیت آبدوستی آن است. در پژوهش حاضر، پلیآکریلو نیتریل به سلولوز به روش پلیمرشدن رادیکالی انتقال اتم (ATRP) پیوند زده شد....
Erythrocytes have been described as advantageous drug delivery vehicles. In order to ensure an adequate circulation half-life, erythrocytes may benefit from protective enhancements that maintain membrane integrity and neutralize oxidative damage of membrane proteins that otherwise facilitate their premature clearance from circulation. Surface modification of erythrocytes using rationally design...
Introduction Highly branched polymers play an increasingly important role in interface and surface sciences, since their distinctive chemical and physical properties can be used advantageously as functional surfaces and as interfacial materials. Hyperbranched polymers grafted onto surfaces have also become a field of growing interest. Depending upon the substrates, it can be divided into 3D, 2D...
Protein patterning was carried out using a simple procedure based on photolithography wherein the protein was not subjected to UV irradiation and high temperatures, or contacted with denaturing solvents, and strongly acidic or basic solutions. Self-assembled monolayers of poly(ethylene glycol) (PEG) on silicon surfaces were exposed to oxygen plasma through a patterned photoresist. The etched re...
Single-walled carbon nanotubes (SWNT) were functionalized with polystyrene (PSt) by grafting to and grafting from methods. PSt-N3 with designed molecular weight and narrow molecular weight distribution was synthesized by atom transfer radical polymerization (ATRP) of styrene (St) followed by end group transformation and then added to SWNT. The grafting from functionalization was achieved by ATR...
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