Much attention has recently been focused on soft porous crystals, a fascinating subclass of metal−organic frameworks that behave in a remarkable stimuliresponsive fashion, presenting structural changes of large amplitude in response to guest adsorption, mechanical pressure, or variations in temperature. In this Perspective, we summarize the recently developed thermodynamic and mechanical theore...

Grape pomace (pulp and skins) was investigated as a new biosorbent for removing mycotoxins from liquid media. In vitro adsorption experiments showed that the pomace obtained from Primitivo grapes is able to sequester rapidly and simultaneously different mycotoxins. Aflatoxin B1 (AFB1) was the most adsorbed mycotoxin followed by zearalenone (ZEA), ochratoxin A (OTA), and fumonisin B1 (FB1), wher...

We present a new class of sequential adsorption models in which the adsorbing particles reach the surface following an inclined direction (shadow models). Capillary electrophoresis, adsorption in the presence of a shear, and adsorption on an inclined substrate are physical manifestations of these models. Numerical simulations are carried out to show how the new adsorption mechanisms are respons...

Using the nonlocal density functional theory, we investigate adsorption of N2 (77 K), Ar (77 K), and CO2 (273 K) and respective adsorption-induced deformation of microporous carbons. We show that the smallest micropores comparable in size and even smaller than the nominal molecular diameter of the adsorbate contribute significantly to the development of the adsorption stress. While pores of app...

expanded graphite nanosheets (eg-nanosheets) were used for adsorption of malachite green (mg) from aqueous solution. the influences of dye concentrations, absorbent dosage, ph values and the temperatures on the adsorption were investigated as well. the dye adsorption experiments were carried out by utilizing batch procedure. eg-nanosheets were initially characterized by scanning electron micros...

This study investigates the capacity of granular activated carbon (GAC) for the storage of methane through the equilibrium adsorption. An experimental apparatus consist of a dual adsorption vessel was set up for the measurement of equilibrium adsorption of methane on GAC using volumetric technique (pressure decay). Experimental isotherms of methane adsorption were determined by the measurement ...

adsorption of p-nitrophenol by three different activated carbons (f100, s.e.i. and b.d.h.) was carried out at 301 k and at controlled ph conditions. two different adsorption models (langmuir model and freundlich model) were studied and compared. the adsorption capacity of the carbons depends on the point of zero charge (pzc) and surface area of the carbons. adsorption of the solute at higher ph...

Abstract With increasing nitrogen purity, PSA plants require an over-proportional air demand with the consequence that high-purity systems engender a distinct interest in energy-saving measures. This paper presents process intensification strategies focus on reduced energy consumption. Therefore, influence of configuration and cycle organisation performance was investigated. Results are present...