A moving, solidifying interface that grows by the instantaneous adsorption of a diffusing solute is described by the classic one-sided “Stefan problem” [15, 19]. More generally, the behavior of precipitate growth can depend on both surface kinetics and bulk drift of the depositing species. We generalize the Stefan problem and its interface boundary condition to explicitly account for both surfa...

the performance of msu-s and its forms modified with phosphotungstic acid (hpw) and nickel (ni) for the desulfurization and denitrogenation of model diesel fuel were studied. according to the results of the characteristic tests (n2 adsorption-desorption, xrd, sem, and nh3-tpd), heteropoly acid incorporation causes higher acidity along with a negligible loss of structural aspects, while ni impre...

Adsorption process is an important technique in separation processes, which is used in heavy metals removal from aqueous solution. Orange peel has been investigated for the adsorption of uranium ions from aqueous solution. The parameters of pH, contact time, initial uranium ion concentration, temperature and adsorbent dose have been investigated in batch experiments. The adsorption kinetics wer...

Using thermal desorption mass spectrometry, we have shown unambiguously that the adsorption of atomic hydrogen on Si(100)-s2 3 1d leads to hydrogen pairing on silicon dimers at surface temperatures as low as 150 K and coverages as low as 0.2 monolayer. A detailed study of the adsorption kinetics shows a high probability of an abstraction reaction together with a coverage-dependent adsorption pr...

We present a theoretical model for the description of the adsorption kinetics of globular proteins onto charged core-shell microgel particles based on Dynamic Density Functional Theory (DDFT). This model builds on a previous description of protein adsorption thermodynamics [Yigit et al., Langmuir, 2012, 28], shown to well interpret the available calorimetric experimental data of binding isother...

This study was aimed to investigate the amount of reactive blue 29 (RB29) dye removal from aqueous solution by Chitosan extracted from Persian Gulf shrimp shell. The effect of parameters such as pH, the concentration of reactive blue 29 dye, contact time, and adsorbent dosage in dye removal was studied. Isotherm, Thermodynamics, and kinetics of adsorption process were also investigated. The...

ADSORPTION OF COPPER(II) BY PEANUT HULLS IN A FIXED-BED, CONTINUOUS FLOW COLUMN Tyler Stephen Cook, Masters of Science in Chemistry Western Carolina University (April 2017) Advisor: Dr. Carmen L. Huffman Heavy metal pollution is an important concern due to its adverse health and environmental effects. Biosorption is a way to remove heavy metals from aqueous systems with the use of biomaterials....

Phenol components are major industry contaminants of aquatic environment. Among all practical methods for removing phenol substances from polluted water, activated carbon absorption is the most effective way. Here, we have produced low-cost activated carbon using Polygonum orientale Linn, a wide spreading species with large biomass. The phenol adsorption ability of this activated carbon was eva...

Nonspecific protein adsorption generally occurs on any solid surfaces and usually has adverse consequences. Adsorption of proteins onto a solid surface is believed to be the initial and controlling step in biofouling. Surfaces modified with end-tethered poly(ethylene glycol) (PEG) have been shown to be protein-resistant to some degree. In this study, the adsorption of β-casein and lysozyme was ...

Nano zerovalent iron (nZVI) is an effective adsorbent for removing various organic and inorganic contaminants. In this study, nZVI particles were used to investigate the removal of Cd(2+) in the concentration range of 25-450 mg L(-1). The effect of temperature on kinetics and equilibrium of cadmium sorption on nZVI particles was thoroughly examined. Consistent with an endothermic reaction, an i...