The title compound, C(14)H(18)N(2)O(3)S, crystallizes in the thio-amide form with an intra-molecular N-H⋯O hydrogen bond associated with the thio-urea unit. With the benzoic acid and the butyrylthio-ureido units, the mol-ecule consists of two planar building blocks connected by the common NH function adjacent to the aromatic ring. The inter-planar angle is 33.38 (3)°. Mol-ecules are connected i...

2 Definitions  Neurofilaments: Nf are proteins which are exclusively expressed in neurons and their adjacent axons. Nf are particularly abundant in the axon, where they are key building blocks of the axonal cytoskeleton. The complex protein chemistry of Nf is briefly described.  Biomarker: A biomarker is a characteristic that is objectively measured and evaluated as an indicator of normal b...

We have synthesized an amphiphilic triblock coil-rod-coil molecule consisting of a rigid aromatic building block and poly(ethylene oxide). The coil-rod-coil molecule was observed to assemble into a cylindrical micelle structure in aqueous solution. Notably, addition of a small amount of a rod-coil-rod molecule into the cylindrical micellar solution can induce the anisotropic gelation due to dyn...

studies on vegetation changes of rangelands under grazed and non-grazedconditions are of great importance in the range management planning programs. to determinethe change process of vegetation, this study was performed in inche shorezar site of golestanprovince for nine years (1997-2005). the vegetation parameters were measured every year inseveral fixed plots inside and adjacent of exclosures...

The synthesis of an octa-alkoxy substituted isotopically labeled naphthalene derivative, shown to have excellent properties in singlet NMR experiments, is described. This highly substituted naphthalene system, which incorporates an adjacent (13)C spin pair, is readily accessed from a commercially available (13)C2-labeled building block via sequential thermal alkynyl- and arylcyclobutenone rearr...

In the title mol-ecule, C(16)H(23)N(3)O(3), the dihedral angle between the benzimidazole and nitro group planes is 5.34 (9)° and the dihedral angle between the benzimidazole and aliphatic chain mean planes is 73.23 (5)°. The C-C-C-C torsion angles (about 176°) of the nonyl group indicate an all-anti-periplanar conformation. In the crystal, adjacent mol-ecules are linked by pairs of N-H⋯O hydrog...

We present xml Conditional Random Fields (xcrfs), a framework for building conditional models to label xml data. xcrfs are Conditional Random Fields over unranked trees (where every node has an unbounded number of children). The maximal cliques of the graph are triangles consisting of a node and two adjacent children. We equip xcrfs with efficient dynamic programming algorithms for inference an...

Organocatalytic Mannich addition of aldehydes to a formaldehyde-derived iminium species catalyzed by proline-derived chiral pyrrolidines provides beta-amino aldehydes with >/=90% ee. Mechanistic analysis of the proline-catalyzed reactions suggests that non-hydrogen-bonded ionic interactions at the Mannich reaction transition state can influence stereochemical outcome. The beta-amino aldehydes f...

This paper proposes a Lyapunov-based economic MPC scheme for nonlinear sytems with non-monotonic Lyapunov functions. Relaxed Lyapunov-based constraints are used in the MPC formulation to improve the economic performance. These constraints will enforce a Lyapunov decrease after every few steps. Recursive feasibility and asymptotical convergence to the steady state can be achieved using Lyapunov-...

in this research, we investigated basic symptoms of syndrome in illnesses of sick buildings. we designed a questionnaire and asked from male of dormitory residence. questions of the questionnaire were more about known symptoms of buildings (shortness of breath, inflammation, swelling and burning eyes, runny nose, malaise and fatigue, drowsiness, headache) exacerbations time intervals in the res...