In a remarkable series of experiments, Elssner et al. (1994) and Korn et al. (2002) observed cleavage cracking along a bimaterial interface between Nb and sapphire. The stress required for cleavage cracking is around the theoretical strength of the material. Classical plasticity models fall short to reach such a high stress level. We use the conventional theory of mechanism-based strain gradien...

High performance concrete (HPC) bridge decks are prone to premature cracking if movement is restrained. Internal curing (IC) can reduce shrinkage cracking in concrete structures, thus improving their performance and service life. However, there is very limited information available in the literature on the possible extension of service life due to internal curing. This paper addresses this ques...

plastic shrinkage is one of the most important parameter which must be considered in hot weather concreting. if plastic shrinkage is not prevented, cracking will be significant, especialy if silica fume is used in the mix. in this paper, the effect of silica fume in bleeding and evaporation was investigated in laboratory. the results showed that in restrained shrinkage, beside relative humidity...

Waste plastics contain a substantial number of valuable chemicals. The wastes from post-consumer as well as from industrial production can be recycled to valuable chemical feedstock, which can be used in refineries and/or petrochemical industries. This chemical recycling process is an ideal approach in recycling the waste for a better environment. Polymer cracking using a laboratory fluidized b...

In situ transmission electron microscopy study of electric field-induced cracking has been conducted on ^001& oriented 0.65Pb~Mg1/3Nb2/3!O3 – 0.35PbTiO3 crystal. Fracture of the 90° domain boundary was directly observed in the tetragonal area under both static and alternating electric fields. The field strength required to induce domain boundary cracking was lower for alternating electric field...

A coupled reactor/furnace simulation has been conducted for a 100 kt/a SL-II naphtha cracking furnace containing both long-flame and radiation burners. The computational fluid dynamics approach was used to simulate the flow, combustion and radiative heat transfer in the furnace. The software packages COILSIM1D and SimCO were used to account for the cracking process in the reactor coils. The sim...

Accurate, non-contact pH sensing is of particular importance in the biological and clinical sciences. Fluorescence lifetime based pH sensing is potentially more useful than intensity based methods because of the reduced sensitivity to excitation source intensity variations, scattering effects, and photobleaching. In this work, we investigate the variation of fluorescence lifetime with pH for re...

Brønsted acid sites in zeolites (H-FER, H-MFI, H-MOR) selectively hydrogenate alkenes in excess H2 at high temperatures (>700 K) and at rates proportional to alkene and H2 pressures. This kinetic behavior and the De Donder equations for non-equilibrium thermodynamics show that, even away from equilibrium, alkene hydrogenation and monomolecular alkane dehydrogenation occur on predominantly uncov...