ROP of bulky functional ?-lactones mediated by an achiral diamino-bis(phenolate) yttrium catalyst affords syndio-enriched polyhydroxyalkanoates.

Bis(1,4-diamino-1,2,4-triazolium) sulfate (1) was obtained from the corresponding chloride by ion metathesis using Ag2SO4. Further metathesis with barium 5,51-azotetrazolate yielded bis(1,4-diamino-1,2,4-triazolium) 5,51-azotetrazolate (2). Numerous NH ̈ ̈ ̈N and NH ̈ ̈ ̈O interactions were identified in the crystal structures of 1 and 2. Both compounds undergo exothermal decomposition upon heating.

the discovery of the antifertility activity of gossypol led scientists and researchers to the development of compounds with antifertility activity that can be used as male contraceptives. these studies resulted in discovery of the antifertility activity of several classes of compounds which have been reported in the literature. this article deals with the synthesis of four new analogues of pyri...

In the centrosymmetric dinuclear complex anion of the title compound, (C(5)H(8)N(3))(2)[Bi(2)(C(7)H(3)NO(4))(4)(H(2)O)(2)]·4H(2)O, the Bi(III) atom is eight-coordinated in an N(2)O(6) environment and has a distorted bicapped trigonal-prismatic coordination environment. Extensive inter-molecular O-H⋯O, N-H⋯O and weak C-H⋯O hydrogen bonds lead to the stability of the crystal structure. Inter-acti...

A fluorescent pyrazine derivative, 3,5-diamino-6-chloro-2-pyrazine carbonitrile (DCPC), is presented as a promising light-up ligand for single-nucleotide polymorphisms (SNPs) typing. In solutions buffered to pH 7.0 (I = 0.11 M, at 5 degrees C), DCPC can bind to thymine selectively over other nucleobases opposite an abasic site in DNA duplexes (5'-GTGTG CGTTG ANA TGGAC GCAGA-3'/3'-CACAC GCAAC TX...

Neat 3,5-dinitro-1H-1,2,4-triazole was obtained in quantitative yield from potassium 3,5-dinitro-1,2,4-triazolate and sulfuric acid. The compound was purified by sublimation in vacuo at 110 °C. Pure HDNT is a hygroscopic white solid that is impact and friction sensitive and decomposes explosively upon heating to 170 °C. However, the presence of impurities might lower the decomposition temperatu...

Co3O4/NiO@GQDs@SO3H nanocatalyst has been used as an effective catalystfor the preparation of 2,4-diamino-6-arylpyrimidine-5-carbonitrile derivativesthrough a three-component reaction of malononitrile, aromatic aldehydes andguanidine hydrochloride under reflux conditions in ethanol. The catalyst has beencharacterized by FT-IR, XRD, SEM, EDS, BET, TGA, XPS and VSM. Atom e...

In this work, the degradation of 2-chloro-4,6-diamino-1,3,5-triazine in aqueous solutions by photo-Fenton process has been investigated. The preliminary results have shown that the degradation of 2-chloro-4,6-diamino-1,3,5-triazine by photo-Fenton process is more rapid and more effective than Fenton and UV/H2O2 processes. The effects of certain experimental parameters on kinetics and efficiency...

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