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A new two-body interaction is derived for nuclei in a large part of the 0flp shell by fitting two-body matrix elements to 494 energy levels in A = 41-66 nuclei. For the shell-model basis a 4°Ca core and a model space consisting of 0~/2 ( lp3/20fs/2 lpl/2)m + 0~7~1 ( lp3/20f5/2 lpl/2) l+ra configurations was assumed. By varying 40 linear combinations of matrix elements and fixing those that are ...

In this review we report on the enantiomerization of tetrahedral racemic-[(NH4)4∩{Mg4(L1)6}] monitored by means variable temperature (VT) 1H NMR spectroscopy. The enantiotopization diastereotopic protons is due to simultaneous Bailar twists at four octahedrally coordinated magnesium centres, synchronized with atropisomerization six edge-bridging ligands (L1)2-.The VT spectrum meso-[In4(L2)4] co...

In the title compound, C22H16ClNO, the quinoline ring system makes dihedral angles of 56.30 (6) and 7.93 (6)°, respectively, with the adjacent phenyl and benzene rings. The dihedral angle between these phenyl and benzene rings is 56.97 (8)°. In the crystal, weak C-H⋯π and π-π [centroid-centroid distances of 3.7699 (9) and 3.8390 (9) Å] inter-actions link the mol-ecules into a layer parallel to ...