the melt-phase synthesis of dioctyltin (iv) and triphenyltin (iv) benzoates were carried outusing stoichiometric amounts of benzoic acids and the corresponding organotin (iv) compounds.the reagents were ground together in a mortar and fed into a boiling glass tube. a cannula tubewas inserted into the boiling tube to discharge accumulated gaseous products. a syringe ensureda continuous flow of d...

The catalytic oxidation of toluene to benzoic acid in the liquid phase has been studied in an un-stirred tank reactor. Low concentration of acetic acid was added in order to increase the solubility of the catalyst in toluene. The dependence of the rate of reaction on the concentration of toluene catalyst and oxygen pressure was studied. It has been suggested that liquid phase oxidation of t...

The title compound, C(16)H(17)N(3)O(2), was synthesized by the reaction of 4-dimethyl-amino-benzaldehyde with 3-hydroxy-benzoic acid hydrazide in methanol. The dihedral angle between the two benzene rings in the mol-ecule is 9.2 (2)°. In the crystal structure, mol-ecules are linked through inter-molecular O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonds, forming layers parallel to the bc plane.

Simple D-hexoses such as D-glucose, D-mannose, and D-galactose were found to form supramolecular complexes with folic acid (FA) in phosphate-buffered saline solution (PBS, pH 7.4) the gas phase. Pterin subunit of FA was be essential for molecular assembly hexoses, whereas PABA (p-amino benzoic acid) GLN (glutamic subunits have virtually no effect on formation. Experimental measurements along DF...

In this study some new compounds have been prepared including thereaction of diazoium salt 1,4-phenylenediamine with 2-mercaptobenzaldehyde at (0-5)0C[F1]. Then Schiff bases [F2-F6] werethen synthesized through the reaction compound [F1] withsubstituteds aniline in absolute ethanol, and were convertedinto 2,3 - dihyroquinazolin 4(1H) one derivatives [F7-F11] by 2-amino benzoic acid ethanol. The...

Although a number of plant natural products are derived from benzoic acid, the biosynthesis of this structurally simple precursor is poorly understood. Hypericum calycinum cell cultures accumulate a benzoic acid-derived xanthone phytoalexin, hyperxanthone E, in response to elicitor treatment. Using a subtracted complementary DNA (cDNA) library and sequence information about conserved coenzyme A...

amino acid dehydrogenases (l-amino acid: oxidoreductase deaminating ec 1.4.1.x) are members of the wider superfamily of oxidoreductases that catalyze the reversible oxidative deamination of an amino acid to its keto acid and ammonia with the concomitant reduction of either nad+, nadp+ or fad. these enzymes have been received much attention as biocatalysts for use in biosensors or diagnostic kit...

Diureidocalix[4]arene have been applied as new ionophore in liquid membrane electrode (ISE) sensitive towards un-dissociated benzoic acid. The electrode demonstrated response towards benzoic acid with the detection limit 2.0 x 10 M which is sufficient for the determination of benzoic acid added to beverages as preservative in milimolar concentration. The selectivity coefficients measured by the...