Reactions of [MoReCp(μ-PMes*)(CO)6] with internal alkynes RC≡CR yielded the phosphapropenylidene-bridged complexes [MoReCp(μ-κ2P,C:η3-PMes*CRCR)(CO)5] (Mes* = 2,4,6-C6H2tBu3; R CO2Me, Ph). Terminal HC≡CR1 gave mixtures isomers [MoReCp(μ-κ2P,C:η3-PMes*CHCR1)(CO)5] and [MoReCp(μ-κ2P,C:η3-PMes*CR1CH)(CO)5], first isomer being major (R1 CO2Me) or unique tBu), indicating relevance steric repulsions ...

(a) Write down the probability distribution of x. Solution: p(x = 0|μ) = 1− μ, so p(x|μ) = μx(1− μ)1−x, this is known as the Bernoulli distribution. (b) Show that this is a proper probability distribution, i.e. the probability sum up to 1. What is the expectation and variance of this distribution? Solution: ∑ x∈{0,1} p(x|μ) = p(x = 0|μ) + p(x = 1|μ) = 1− μ+ μ = 1 E(x) = ∑ x∈{0,1} xp(x|μ) = 0× p...

Background: Cystoid Macular Edema (CME) is one of the most common and sight threatening complications of uveitis. Intravitreal injection of corticosteroids and anti-VEGF antibody are two routine options for treatment. Objective: To compare the effects of intravitreal injections of Bevacizumab and Triamcinolone Acetonide for the treatment of persistent macular edema in non-infectious uveitis. Me...