Kinetic Analysis of the Decomposition of Nitrous Oxide over ZSM-5 Catalysts Freek Kapteijn, Gregorio Marbán,∗ José Rodriguez-Mirasol,† and Jacob A. Moulijn Industrial Catalysis, Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands; ∗Instituto Nacional del Carbon, Oviedo, Spain; and †Department of Chemical Engineering, University of ...

A novel route is proposed for the preparation of mesopore containing zeolite ZSM-5 via in situ hydrothermal treatment of a solution containing alkali-dissolved SBA-15 containing carbonized surfactant P123 in the mesopores; it exhibited prominent stability enhancement for methanol to propylene reaction.

This study aimed to valorize microcrystalline cellulose (MCC) using protonated zeolite catalysts such as (H-ZSM-5) and Cr/H-ZSM-5 (5%) in ionic liquid. The catalytic effect synergy with 1-butyl-3-methylimidazolium Chloride ([BMIM] Cl) liquid was studied detail. total reducing sugar (TRS) determined the 3, 5-dinitrisalcylic acid (DNS) array method. were characterized techniques Fourier transform...

The aim of this work was to establish the effects of zeolite structure/chemical composition on the activity and selectivity of Cu-exchanged Y (Si/Al = 2.5), ZSM-5 (Si/Al = 12), and Mordenite (Si/Al = 10) for the oxidative carbonylation of methanol to DMC. Catalysts were prepared by solid-state ion-exchange of the H-form of each zeolite with CuCl and were then characterized by FTIR and X-ray abs...

lamno3 and lamno3/zsm-5 nano catalysts were synthesized by pechini method and their physical-chemical properties were characterized using xrd, ftir, sem-edx, uv-vis drs, bet surface area and tpr. the correlation between characteristic properties and activity of catalysts were investigated. the catalytic performance of the catalysts was evaluated in combustion of 2-propanol and compared with 1% ...

The Al siting in the ZSM-5 zeolite was investigated by Al 3Q MAS NMR spectroscopy and QM/MM calculations. It was found that the occupation of the framework T-sites by Al and the concentration of Al in these T-sites are neither random nor controlled by a simple rule. They both depend on the conditions of the zeolite synthesis. At least 12 out of the 24 distinguishable framework T-sites of ZSM-5 ...