نتایج جستجو برای: π stacking
تعداد نتایج: 44075 فیلتر نتایج به سال:
In the crystal of the title compound, C(14)H(11)N(2)O(2) (+)·C(7)H(7)O(3)S(-), the cation and anion inter-act by way of an aromatic π-π inter-action [centroid-centroid separation = 3.5783 (2) Å] and a T-stacking (C-H⋯π) inter-action between cations. The dihedral angle between the aromatic rings in the cation is 61.73 (8)°. The ionic units are aligned in a zigzag fashion in the b-axis direction.
The complete molecule of the title compound, C(16)H(14)F(6)N(2)O(2), is generated by crystallographic inversion symmetry, which results in two short intramolecular C-H⋯N hydrogen-bond contacts per molecule. In the crystal, aromatic π-π stacking [centroid-centroid distance = 3.457 (2) Å] and weak C-H⋯π inter-actions occur. A short H⋯H [2.32 (3) Å] contact is present.
In the title mol-ecule, C18H19BrN2O, the benzene ring is inclined to the oxa-diazole ring by 10.44 (8)°. In the crystal, C-H⋯π inter-actions link the mol-ecules in a head-to-tail fashion, forming chains extending along the c-axis direction. The chains are further connected by π-π stacking inter-actions, with centroid-centroid distances of 3.6385 (7) Å, forming layers parallel to the bc plane.
The discovery of new histone modifications is unfolding at startling rates; however, the identification of effectors capable of interpreting these modifications has lagged behind. Here we report the YEATS domain as an effective reader of histone lysine crotonylation, an epigenetic signature associated with active transcription. We show that the Taf14 YEATS domain engages crotonyllysine via a un...
The non-H atoms of the title mol-ecule, C10H10N2O, are essentially coplanar, with a maximum deviation of 0.046 (4) Å for the O atom. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds, forming chains along [010]. In addtion, weak C-H⋯π inter-actions and π-π stacking inter-actions between benzene and pyrimidine rings, with a centroid-centroid distance of 3.730 (3) Å, link the cha...
The title compound, C(14)H(11)Br(2)NO, was prepared by the condensation of benzyl-amine and 3,5-dibromo-2-hydroxy-benzaldehyde. The crystal structure is stabilized by aromatic π-π stacking inter-actions between the phenol rings of neighbouring mol-ecules [centroid-centroid distance = 3.530 (5) Å]. In addition, the stacked mol-ecules exhibit inter-molecular C-H⋯π and intra-molecular O-H⋯N inter-...
The title mol-ecule, C12H12N2OS, is planar, with an r.m.s. deviation of 0.04 Å. In the crystal, the N atom adjacent to the carbonyl group is sp (2)-hybridized. The crystal structure is stabilized by π-π stacking inter-actions observed between thio-phene and pyrimidinone rings of c-glide-related mol-ecules [centroid-centroid distance = 3.9554 (13) Å] and by C-H⋯π inter-actions, forming an infini...
In the title compound, C(16)H(12)O(2)S, the phenyl ring is nearly perpendicular to the naphthalene system [dihedral angle = 80.3 (1)°]. The packing is consolidated by a weak C-H⋯π inter-action involving neighbouring naphthalene and benzene rings. In addition, there exist two different offset π-π stacking inter-actions between benzene rings and between naphthalene systems of symmetry-related mol...
In the title compound, C(15)H(12)N(4)O(2), the dihedral angle between the planes of the nicotino-yloxy fragment and triazole ring is 88.61 (5)°. The dihedral angle between the planes of triazole and benzene rings is 16.54 (11)°. The crystal structure is stabilized by inter-molecular C-H⋯N, C-H⋯O and C-H⋯π(triazole) hydrogen bonds and aromatic π-π stacking inter-actions between the benzene and t...
The title compound, C(15)H(13)N(5), crystallizes with two independent mol-ecules in the asymmetric unit. The mol-ecular conformations are stabilized by C-H⋯N contacts forming S(6) ring motifs. In the crystal, pairs of mol-ecules are connected into R(2) (2)(12) dimers by N-H⋯N hydrogen bonds. C-H⋯π inter-actions and π-π stacking inter-actions [centroid-centroid distances = 3.6085 (8), 3.6657 (8)...
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