Zinc porphyrins possessing three p-carboxyphenyl anchoring groups with various substituents were prepared by a facile three-step route in good yields. Zn1NH3A with electron donating and anti-aggregation meso substituents has achieved the highest efficiency of 6.10%. These porphyrins with three p-carboxyphenyl groups are more stable toward photo-bleaching than their single anchoring group analogs.

This paper presents a new approach for flotation circuit design. Initially, it was proven numerically and analytically that in order to achieve the highest recovery in different circuit configurations, the best equipment must be placed at the beginning stage of the flotation circuits. The size of the entering particles and the types of streams including pulp and froth were considered as the bas...

Although engineering of transcription factors and DNA-modifying enzymes has drawn substantial attention for artificial gene regulation and genome editing, most efforts focus on affinity and specificity of the DNA-binding proteins, typically overlooking the kinetic properties of these proteins. However, a simplistic pursuit of high affinity can lead to kinetically deficient proteins that spend t...

aims: municipal landfill leachate contains high concentrations of heavy metals, organics, ammonia . t he efficeincy of electrochemically removal of heavy metals from landfill leachate was studied. materials & methods: the leachate was obtained from kahrizak landfill in south of tehran. the experiments were carried out by batch process. the 2liter batch reactor was made of glass. there were eigh...

Zinc messenger Z inc has always had its fi ngers in the structure and activity of enzymes, transcription factors, and signaling molecules. Now, Yamasaki et al. (page 637) fi nd zinc also working as a second messenger capable of converting an external signal into internal events. When the authors created an external signal in mast cells by cross-linking IgE receptors, they observed an internal w...

A choline chloride-urea (ChCl-urea) deep eutectic solvent (DES) was used to experimentally investigate the secondary recovery of zinc from zinc-bearing dust sludge via a leaching process. The effects varying liquid–solid ratio, temperature, stirring speed, and time on efficiency were determined, optimum values these parameters found be 15:1, 90 °C, 400 rpm, 600 min, respectively, at which 86.87...

Aqueous zinc-ion batteries possess great potential in stationary energy storage devices. Nevertheless, the occurrence of zinc dendrite growth and hydrogen evolution reaction severely hinders utilization efficiency service life zinc-metal anodes. Herein, an situ etching strategy is proposed to construct interfacial layer with porous structure on surface foil under assistance tartaric acid (denot...

Nano fertilizers are new products which contain readily available nutrients in the nano scale range and are preferred largely due to their efficiency. This research was conducted to assessment the effect of nano chelated of micro nutrient on agronomic traits of Cowpea via factorial experiment based on randomized complete block design with four replications during 2016 seasonal year. The treatme...