The Kirkendall effect and Ostwald ripening were successfully combined to prepare uniquely structured NiO aggregates. In particular, a NiO-C composite powder was first prepared using a one-pot spray pyrolysis, which was followed by a two-step post-treatment process. This resulted in the formation of micron-sized spherical and hollow-structured NiO aggregates through a synergetic effect that occu...

The fabrication process of ceramic yttria-stabilized zirconia (YSZ) and nickel oxide nanofibers by electrospinning is reported. The preparation of hollow YSZ nanofibers and aligned nanofiber arrays is also demonstrated. The influence of the process parameters of the electrospinning process, the physicochemical properties of the spinning solutions, and the thermal treatment procedure on spinnabi...

A new input/output (NIO) library that provides block-oriented I/O was introduced with Java v1.4. Because of its complexity, creating network applications with the Java NIO library has been very difficult and build-in support for high-performance, distributed and parallel systems was missing. Parallel architectures are now becoming the standard in computing and Java network application programme...

Nickel oxide (NiO) and phosphotungstic acid (PTA) supported on a ZIF-8 (NiO-PTA/ZIF-8) catalyst was first synthesized and it showed high activity and good selectivity for the hydrocracking of Jatropha oil. The catalyst was characterized by SEM, SEM-EDS, TEM, N2 adsorption, FT-IR, XRD and XPS. Compared with the NiO-PTA/Al2O3 catalyst, the selectivity of C15-C18 hydrocarbon increased over 36%, an...

This paper reports the effect of post-laser irradiation on the gas-sensing behavior of nickel oxide (NiO) thin films. Nanocrystalline NiO semiconductor thin films were fabricated by a sol-gel method on a nonalkaline glass substrate. The NiO samples were irradiated with a pulsed 532-nm wavelength, using a Nd:YVO(4) laser beam. The effect of laser irradiation on the microstructure, electrical con...

Without sensing any physical force, a neutral object in an ion conducting solid can move in a uniform electrochemical fi eld by coupling a global ion wind with localized counterion diffusion at the interface. This happens to pores and gas bubbles at 840 ° C in a fast O 2– conductor, yttria-stabilized zirconia (YSZ), despite having cations that are essentially frozen with lattice diffusivities 1...

Cathodic and anodic overpotentials were measured using current interruption and AC impedance spectroscopy for two separate solid oxide fuel cells (SOFCs). The fuel cells used yttria-stabilized zirconia (YSZ) as the electrolyte, strontium-doped lanthanum manganite (LSM) as the cathode, and a porous YSZ layer impregnated with copper and ceria as the anode. The Cu/CeO2/YSZ anode is active for the ...

This paper reviews recent work on SOFC anode fabrication at the University of Pennsylvania. In this work, anode fabrication is based on the preparation of a porous YSZ matrix, into which electronic and catalytic components are added by impregnation of the appropriate metal salts. First, the methods used to prepare porous YSZ are described, along with a description of the structures that are obt...

AbstractIn this study, the stress analysis of YBCO/CeO2/YSZ/CeO2/Ni architextured materials under cryogenic conditions was carried out for coated conductor applications. YBCO/CeO2/YSZ/CeO2 multilayer films were fabricated on Ni tape substrate using reel-to-reel sol-gel and Pulse Laser Deposition (PLD) systems. The microstructural evolution of high temperature superconducting YBCO film and buffe...

Catalytic methane combustion was carried out over YSZ, Pd/YSZ and Rh/YSZ between 200 700 °C. Despite similar light-off curves for 450 °C, isotopic exchange experiments using CD4 18O2 revealed different behaviour of both supported catalysts regarding the activation reactant molecules. The use C18O2 gas shown to be more appropriate than evaluate bulk oxygen mobility in YSZ at low temperatures. ga...