A scaling model is presented to analyze the nonlinear rheology of unentangled polymer melts filled with high concentration of small spherical particles. Assuming the majority of chains to be reversibly adsorbed to the surface of the particles, we show that the emergence of nonlinearity in the viscoelastic response of the composite system subjected to a 2D shear flow results from stretching of t...

We report on the characterization of nanometer-scale torsional devices based on individual single-walled carbon nanotubes as the spring elements. The axial shear moduli of the nanotubes are obtained through modeling of device reaction to various amounts of applied electrostatic force and are compared to theoretical values.

In this article a practical mass-spring system was developed to simulate the draping of woven and knitted fabrics. The material properties important to fabric drape, including aerial density, tensile, shear, and bending properties were measured using the Kawabata Evaluation System and the experimental data were incorporated into the mass-spring model to simulate the dynamic draping behavior of ...

Hydraulic cements develop mechanical strength and low permeability as a result of hydration, which involves chemical reactions between water and the anhydrous compounds present in the cement. Solid hydration products form both at the surfaces of the cement particles and in the pore space by nucleation and aggregation. As a result, the solid phase becomes highly connected and the material transf...

The five independent elastic moduli of extruded rods of two thermotropic liquid crystalline polymers, Vectra B900 and Vectra A950, and the nine independent moduli of an injection-moulded bar of Vectra A950 have been measured by ultrasonic methods at 10 MHz. For Vectra B900, the sharp rise in the axial extensional modulus C33 and the moderate drop in the transverse modulus C 11 with increasing d...

We have determined the mechanical anisotropy of a single microtubule by simultaneously measuring the Young's and the shear moduli in vitro. This was achieved by elastically deforming the microtubule deposited on a substrate tailored by electron-beam lithography with a tip of an atomic force microscope. The shear modulus is 2 orders of magnitude lower than the Young's, giving rise to a length-de...

R. Sinkus, K. Siegmann, T. Xydeas, M. Tanter, M. Fink Laboratoire Ondes et Acoustique, ESPCI, Paris, France, Universitätsklinikum Tübingen, Tübingen, Germany Synopsis 3D steady-state MR-Elastography is utilized to assess the transverse isotropic properties of benign and malignant breast lesions. Both shear moduli as well as the local fibre-orientation are reconstructed. Attenuation effects are ...

Configurations of supercooled liquids residing in their local potential minimum (i.e., in their inherent structure, IS) were found to support a non-zero shear stress. This IS stress was attributed to the constraint to the energy minimization imposed by boundary conditions, which keep size and shape of the simulation cell fixed. In this paper, we further investigate the influence of these bounda...

It is shown that the shoving model expression for the average relaxation time of viscous liquids, according to which the activation energy is proportional to the instantaneous shear modulus, follows largely from a classical "landscape" estimation of barrier heights from curvature at energy minima. Although the activation energy in this reasoning involves both instantaneous bulk and shear moduli...