The oxygen isotope fractionation factors between the hydration complex of the alkali ions in the gas phase and a free water molecule have been computed on the basis of the energy surfaces calculated by Kistenmacher, Popkie and Clementi for a water molecule in the field of an alkali ion. For comparison with recently measured oxygen isotope fractionation factors in aqueous alkali halide solutions...

A MICROSCOPIC theory of the kaol ini te-water system is presented, based upon the assumption t ha t the clay-water interaction may be envisioned as par t ly hydrat ion of the exchangeable cations and par t ly adsorption by the oxygen and hydroxyl surfaces. The theory t reats exchangeable cation hydrat ion quantum-mechanically as an ion-dipole phenomenon and considers water adsorption by the min...

In this study, biodegradable kefiran-chitosan-nanocellulose blend films were developed and their physical, mechanical, barrier, thermal and structural properties determined. Results showed that adding nanocellulose had not any significant effect on the thickness, moisture content and water solubility. Also, water vapor permeability, tensile strength and lightness increased and the elongation at...

The current–voltage characteristics of a proton exchange membrane (PEM) electrolyzer constructed with an IrRuOx water oxidation catalyst and a Pt black water reduction catalyst, under operation with water vapor from a humidified carrier gas, have been investigated as a function of the gas flow rate, the relative humidity, and the presence of oxygen. The performance of the system with water vapo...

Physical properties as well as antimicrobial activities against Escherichia coli O157:H7, Salmonella enterica, and Listeria monocytogenes of allspice, garlic, and oregano essential oils (EOs) in tomato puree film-forming solutions (TPFFS) formulated into edible films at 0.5% to 3% (w/w) concentrations were investigated in this study. Antimicrobial activities were determined by 2 independent met...

In this paper, taking account of the major physical and chemical mechanisms, such as: for polymer, shearing propertypermeability reduction, adsorption, inaccessible porous volumes, for gel, gelation speed, water viscosity changing with gel, permeability reduction, adsorption and retention in reservoir rocks, a three-dimensional, three-phase (oleic, vapor, aqueous) and six-component mathematical...

Gelatin composite films were prepared from gelatin solutions (10% w/v) containing multi-walled carbon nanotubes (MWCNT, 0.5, 1, 1.5, and 2% w/w gelatin) as nanofiller. The water solubility, water swelling, water uptake, water vapor permeability (WVP), mechanical, and antibacterial properties of the films were examined. Water solubility, water swelling, water uptake, and WVP for gelatin films we...

The conversion of biomass to a lowor medium-heating-value gaseous fuel (biomass gasification) generally involves two processes. The first process, pyrolysis, releases the volatile components of the fuel at temperatures below 600°C (1,112°F) via a set of complex reactions. Included in these volatile vapors are hydrocarbon gases, hydrogen, carbon monoxide, carbon dioxide, tars, and water vapor. B...

We present a laser-based system to measure the refractive index of air over a long path length. In optical distance measurements, it is essential to know the refractive index of air with high accuracy. Commonly, the refractive index of air is calculated from the properties of the ambient air using either Ciddor or Edlén equations, where the dominant uncertainty component is in most cases the ai...