the complexation of alkali metal cations by the water-soluble p-sulfonic acid calix(4)arenewas thermodynamically characterized using spectrophotometeric data which are consistentwith the formation of a 1:1 complex resulting from electrostatic interactions between thesulfonato groups and alkali metal cations. in this study, we determined the formationconstants (log k) of the complexes and have c...

The molecular code of specific DNA recognition by proteins as a paradigm in molecular biology remains an unsolved puzzle primarily because of the subtle interplay between direct protein-DNA interaction and the indirect contribution from water and ions. Transformation of the nonspecific, low affinity complex to a specific, high affinity complex is accompanied by the release of interfacial water ...

nano dithiocarbamate (dtc) complex have been prepared by reaction between dithiocarbamate and metal salt under ultrasound irradiation. reaction conditions such as the ligand dtc and phennantroline concentration, aging time and the ultrasonic device power show important roles in the size, morphology and growth process of the final products. the dithiocarbamate complex nanoparticles have been pre...

Background & Aims of the Study: Drinking polluted water can transmit diseases, so potable water treatment is one of the most challenging and complex systems in countries. Continuous monitoring for evaluation process in water treatment plant is important. This study aims to investigate performance evaluation of Qom water treatment plant to remove turbidity and coliform in 2005 - 2014. Materia...

acanthophyllum laxiusculum is one of the most widely distributed species of the genus in iran that flourishes in steppe and mountainous regions of the country. in the present study, water-soluble content of a. laxiusculum roots was extracted by boiling water and further successively purified partially by a defined solvent system. surface tension measurements revealed the ability of plant extrac...

The complex [Ru(bpy)2L] , where bpy = 2,2’-bipyridine, L = 4-(phenylethynyl)-2,2’-bipyridine, was prepared in its racemic and resolved forms (and . The phenylethynyl unit on the bipyridine for the complex acts as a binding site for -cyclodextrin in water (1:1 complex, K = 3390 M) or -cyclodextrin (2:1 complex, K1 = 887 M , K2 = 8070 M ). The presence of the cyclodextrin provides partial p...

To date, it has not been possible to measure microscopic diffusive water movements in epithelia and in the interstitial space of complex tissues and organs. Diffusive water movements are essential for life because they convey physiologically important small molecules, e.g. nutrients and signaling ligands throughout the extracellular space of complex tissues. Here we report the development of a ...

In this paper, we examine the demand for fresh water of China in 2025 from the complex system modeling perspective and we develop an efficient, economical and practical water strategy to meet the demand for fresh water in 2025.Different from previous research, this study focus on studying several factors that can influence the demand for fresh water, and their interplay within the complex large...

Vinblastine is an important anticancer agent known to diminish microtubule assembly. Ab initio calculations are applied to examine the structural properties and different energies of vinblastine-tubulin complex in different dielectric constants and temperatures. The aims of this work are discovery the best optimized structure and thermodynamic properties of vinblastine-tubulin complex ...