This study aimed to valorize microcrystalline cellulose (MCC) using protonated zeolite catalysts such as (H-ZSM-5) and Cr/H-ZSM-5 (5%) in ionic liquid. The catalytic effect synergy with 1-butyl-3-methylimidazolium Chloride ([BMIM] Cl) liquid was studied detail. total reducing sugar (TRS) determined the 3, 5-dinitrisalcylic acid (DNS) array method. were characterized techniques Fourier transform...

In order to improve the adsorption performance of molecular sieve honeycomb ceramics for VOCs, author proposes a research method VOCs based on loaded with sieves. The prepared cordierite ceramic-supported HY, Na Y, USY, ZSM-5-300, and ZSM-5-360 monolithic materials by coating method. Using toluene, ethyl acetate, isopropanol, acetone as adsorbates, properties single-component mixed-component or...

Comparative studies over micro-/mesoporous Cu-containing zeolites ZSM-5 prepared by top-down treatment involving NaOH, TPAOH or mixture of NaOH/TPAOH (tetrapropylammonium hydroxide) were conducted. The results the catalytic data revealed highest activity Cu-ZSM-5 catalyst both in absence and presence water vapor. physico-chemical characterization (diffuse reflectance UV-Vis (DR UV-Vis), Fourier...

An ultrasonic treatment was applied to the vacuum gas oil at intervals of 5 30 minutes, 70°C. In this work, improvement important properties Iraqi oil, such as carbon residue, studied with several parameter conditions that affect efficiency, sonication time (5, 10, 15, 20, 25, and 30) min, power amplitude (10–50%). After treatment, residue evaluated using a Conradson meter (ASTM D189). The expe...

The realization of biofuels and chemicals requires the development highly active selective catalysts, which are resistant to deactivation. A conventional ZSM-5 (SiO2/Al2O3 = 30) was modified with 0.2 M NaOH generate a mesoporous zeolite support. parent zeolite, mic-ZSM-5, hie-ZSM-5, silica support, SiO2, were impregnated 5% nickel characterized using X-ray powder diffraction (XRD), Brunauer–Emm...

Medium-pore (diameter ~ 6A) zeolites such as ZSM-5 and silicalite impregnated with Group VIII metals provide selective catalytic pathways for the conversion of synthesis gas to gasoline or olefins. Mössbauer and magnetic studies on these catalysts containing iron or iron plus cobalt are reported. The zeolites were impregnated with metal nitrate solutions, reduced, and carbided to yield showed F...

Catalytic pyrolysis behavior of synthesized microporous catalysts (conventional Zeolite Socony Mobil–5 (C-ZSM-5), highly uniform nanocrystalline ZSM-5 (HUN-ZSM-5) and β-zeolite), Mesoporous catalysts (highly hydrothermally stable Al-MCM-41 with accessible void defects (Al-MCM-41(hhs)), Kanemite-derived folded silica (KFS-16B) and well-ordered Al-SBA-15 (Al-SBA-15(wo)) were studied with waste po...

Zeolite ZSM-5 presents a great source of interest in catalysis because of its shape selective properties. The absence of a relationship between the template size and shape of the structure generated during the synthesis of zeolites is illustrated by the case of ZSM-5. In this study, we have investigated the role of ethanol, methyltriphenylphosphonium bromide (MTPBr) and cetyltrimethylammonium b...

The vacuum residue fraction of petroleum, comprising material with a normal boiling point of over 524°C, is a complex mixture of components with a wide range of molecular weight and chemical structure. The emphasis in process development and design for conversion of the vacuum residue fraction has tended to focus on the chemistry of the feed and the cracked products, and to some extent the chem...