Using PSPICE a resonant dc-dc converters operating at constant frequency was simulated. The paper concentrates on the working of a half bridge topology employing ZVS techniques. The operation of converter with LC filter in the output is discussed. The design and fabrication was done on a 5V, 50W converter using MOSFET to validate the performance of the converter. The converter has illustrated l...

Unsymmetrical dimethylhydrazine (UDMH) is very toxic and hard to decompose in traditional ways. In this paper, the gasification of unsymmetrical supercritical water was studied a batch reactor under different conditions. The hydrogen production process UDMH metal containers multiphase reaction process. effects temperature, alkaline catalysts, residence time, oxidation on were systematically stu...

Unsymmetrical ketones and allyltitanocenes generated by the desulfurizative titanation of γ,γ-disubstituted allyl phenyl sulfides react under highly diastereoselective construction of adjacent quaternary stereocenters (see scheme; R(L) = large group, R(S) = small group). The title reaction is stereospecific: the anti- and syn-homoallylic alcohols are obtained by the reaction of E- and Z-allylic...

The selective formation of a single isomer of a [3+2] self-assembled organic cage from a reaction mixture of an unsymmetrical aldehyde and a flexible amine is discussed. The experimental and theoretical findings suggest that in such a process, the geometric features of the aldehyde play a key role.

An unsymmetrical subphthalocyanine trimer consisting of three different subphthalocyanine units was synthesized. Its optical and physical properties were investigated by UV/Vis, fluorescence spectrometry, cyclic voltammetry and computations. Energy transfer from the non-substituted subphthalocyanine unit to the perfluorinated subphthalocyanine unit via a trifluoroethoxy substituted unit is sugg...

The transient heating in an unsymmetrical coated hot–strip sensor was simulated with a self–adaptive finite element method. The first tests of this model show that it can determine with a small error the thermal conductivity of liquids, from the transient temperature rise in the hot–strip, deposited in a substrate and coated by an alumina spray.

A highly enantioselective direct Mannich reaction of methyl alkyl ketones with cyclic imines benzo[e][1,2,3]oxathiazine 2,2-dioxides, catalyzed by the combination of cinchona alkaloid derived primary amine and TFA, is disclosed. For unsymmetrical methyl alkyl ketones, it is favoured that specific regioselective addition to the imine substrates occurs at the less-substituted methyl group by ster...

The title compound, C(26)H(21)N(3)O(2), is an unsymmetrical tetra-dentate Schiff base ligand. The hydr-oxy group forms an intra-molecular O-H⋯N hydrogen bond with an adjacent N atom. An inter-molecular N-H⋯O hydrogen bond creates centrosymmetric dimers in the crystal packing.

An efficient and practical method to a wide range of perfluorinated unsymmetrical diarylmethanes with good to excellent yields and high regioselectivities has been developed by Pd-catalyzed direct benzylation of highly electron-deficient perfluoroarenes; excellent compatibility of functional groups has also been established.