Novel vitamin E chelate siderophore derivatives and their VV FeIII complexes have been synthesised the chemical biological properties evaluated. In particular, α- δ-tocopherol with bis-methyldroxylamino triazine (α-tocTHMA) (δ-tocDPA) as well complexes, [V2VO3(α-tocTHMA)2] [V2IVO3(δ-tocTHMA)2], characterised by infrared (IR), nuclear magnetic resonance (NMR), electron paramagnetic (EPR) ultra v...