The full-spectrum k-distribution (FSK) approach has become a promising method for radiative heat transfer calculations in strongly nongray participating media, due to its ability to achieve high accuracy at a tiny fraction of the line-by-line (LBL) computational cost. However, inhomogeneities in temperature, total pressure, and component mole fractions severely challenge the accuracy of the FSK...

It is proposed that xanthophylls, and carotenoids in general, may assist in energy transfer from the chlorophyll Soret band to the Q band. Ground-state (1Ag ) and excited-state (1Bu ) optimizations of violaxanthin (Vx) and zeaxanthin (Zx) are performed in an environment mimicking the light-harvesting complex II (LHCII), including the closest chlorophyll b molecule (Chl). Time-dependent density ...

A Bodipy based, highly selective probe for hydrogen sulfide has been designed, synthesized and demonstrated to detect H2S in living cells. In this design, the reduction of two arylazido groups change the charge transfer characteristics of the 3,5-distyryl substituents on the Bodipy core, producing a 20 nm bathochromic spectral shift in the absorption band, and quenching of the emission by 85% c...

A retrodirective beamforming system (BFS) based on a Rotman lens is proposed for far-field wireless power transfer at Ka-band. The true-time-delay property of the allows wideband operation covering 28–38 GHz. designed BFS comprises with nine beam ports connected to nine-element linear Vivaldi array. implemented using PCB technology ease manufacturing and low-cost processing. simulated measured ...

Multi-colour emitting doped ZnS nanocrystals surface capped with pyridine (P-ZnS) or polyvinyl pyrrolidone (PVP-ZnS) have been synthesized by wet chemical methods. The photoluminescence studies show that the dopant related emission from P-ZnS nanocrystals are caused by the energy transfer from band-to-band excitation of the host lattice. However, in the case of PVP capped ZnS, considerable enha...

A new ligand that covalently attaches to the surface of colloidal CdSe/CdS nanorods and can simultaneously chelate a molecular metal center is described. The dithiocarbamate-bipyridine ligand system facilitates hole transfer through energetic overlap at the inorganic-organic interface and conjugation through the organic ligand to a chelated metal center. Density functional theory calculations s...