AlIylferrocenylselenide (2) is prepared from diferrocenyldiselenide (ISe) which was characterized along with its sulfur analog IS by X-ray structure analysis. In the crystal lattice the packing is determined by 'point-to-face' CH-"re interactions with close contacts between the CH re donors and cyclopentadienyl rings as the re acceptors. Compound 2 is then used in the trapping of the primary bu...

Photochromic polymeric films were prepared by doping photochromic dye spironaphthooxazine into polymer resin gels such as polyurethane, vinyl copolymer, and copolymer of vinyl and nitorocellulose at different concentrations. All of the composite films show normal photochromism. The kinetics of the photochromism/decoloration in the films were quantified by fitting biexponential equations to thei...

it is possible to develop new biodegradable active packaging by coating biopolymers on paper-based packaging material and also incorporating proper antimicrobial agents into coating structure. in this study bacterial contamination of two commercial cardboard were evaluated.in order to manufacture an appropriate antibacterial packaging material, coating of chitosan-poly vinyl alcohol blends with...

Vinyl functionalized poly (ε-caprolactone) with molar mass ranging from 500–5000 Da were synthesized by ring opening polymerization and further photopolymerized. One-step synthesis and functionalization is achieved based on ring opening polymerization (ROP). Hydroxyl butyl vinyl ether (HBVE) was employed to play the role as the initiator of ROP, and photo-curable functional group. The presence ...

7-hydroxy coumarin undergoes neutral conditions with alkyl propiolates in the presence of triphenylphosphine, and bysubstituation the corresponding aryl vinyl ethers was obtained in good yields

The binding energy and Thermodynamic Parameters of cis- Platinum Di Ammino Chlorine (cis-[Pt(NH3)2Cl]+) and trans- Platinum Di Ammino Chlorine (trans- [Pt(NH3)2Cl]+) complexes withGuanine has been studied by density functional theory (DFT) calculations in water. The bindingenergies (Ebin) of cis- and trans-[Pt(NH3)2ClG]+ are calculated to be 79.38 kcal/mol and 74.98kcal/mol, respectively. The b...

Zirconium oxy-salts were hydrolyzed to form positively charged polymer or cluster species in acidic solutions. The zirconium hydrolyzed polymer was found to react with a negatively charged polyelectrolyte, such as poly(vinyl sulfate), and to form a stoichiometric polyion complex. Thus, colloidal titration with poly(vinyl sulfate) was applied to measure the zirconium concentration in an acidic s...

We have made detailed comparison of the local and chain dynamics of a melt of 1,4-polybutadiene (PBD) as determined from experiment and molecular dynamics simulation at 353 K. The PBD was found to have a random microstructure consisting of 40% cis, 50% trans and 10% 1,2-vinyl units with a number average degree of polymerization = 25.4. Local (conformational) dynamics were studied via measu...

The handling of vinyl polysiloxane (addition silicone) impression putties with latex gloves is said to interfere with the setting of these impression materials. The aim of this study is to evaluate the effect of handling techniques on the setting of vinyl polysiloxane impression putties using several types of gloves. The setting of these materials was evaluated by means of an elasticimeter. Fou...

Bleaching of polymeric materials can be achieved by blending or surface treatment with fluorescent brighteners, FBs [1]. In both cases the FB migrates with time, and the degree of whiteness decreases. The introduction of polymerizable groups into the FB makes it applicable in the copolymerization process with vinyl monomers, resulting in the formation of covalent bonds in the polymer molecule. ...