Solid-phase extraction (SPE) was tested for the isolation of dissolved lignin from diverse natural waters (fresh, estuarine, and marine) in preparation for CuO oxidation. Capillary GC coupled to selected-ion monitoring mass spectrometry (SIM-MS) of CuO oxidation products provides the high sensitivity and precision required for the identification and quantification of trace levels of lignin in s...

Groundwater and sediment samples were collected along a flow path in the Aquia aquifer (Paleocene), Maryland in order to examine and study the factors influencing "evolution" of arsenic (As) in these groundwaters. The Aquia crops out near Washington, DC, where it is unconfined, and extends approximately 90 km down dip to the south and east towards and beneath the Chesapeake Bay. The studied flo...

Although sulfur is an essential element for marine primary production and critical for climate processes, little is known about the oceanic pool of nonvolatile dissolved organic sulfur (DOS). We present a basin-scale distribution of solid-phase extractable DOS in the East Atlantic Ocean and the Atlantic sector of the Southern Ocean. Although molar DOS versus dissolved organic nitrogen (DON) rat...

hydrographically bolivian poopó lake is located in the basin of desaguadero river and it has over a dozen main tributary rivers and other smaller rivers with lower flow. the mine water discharge from the abandoned and current mining activities polluted these rivers by carrying heavy metals, dissolved and suspended solids which in turn polluted the poopó lake which is considered as an important ...

A simple, rapid and sensitive solvent assisted-dispersive solid phase extraction method was developed for the extraction of iron(II) prior to its spectrophotometric determination. The Fe(II) reacted with 2,4,6-tris(2-pyridyl)-1,3,5-triazine, neutralized with sodium dodecyl sulfate and extracted onto the fine particles of benzophenone which were formed upon rapid injection of a mixture of benzop...

Increasing water demand and reducing its contaminations are the main concerns and challenges for water resource managers and planner due to its limited sources and high value. This study aims to assess and understand the factors which threaten the quality of groundwater resources and to achieve this, samples were taken from 14 active wells in District 3 of the Municipality of Tehran. After cate...

In June 2007 sediment cores were collected in Alaminos Canyon, Gulf of Mexico across a series of seismic data profiles indicating rapid transitions between the presence of methane hydrates and vertical gas flux. Vertical profiles of dissolved sulfate, chloride, calcium, magnesium, and dissolved inorganic carbon (DIC) concentrations in porewaters, headspace methane, and solid phase carbonate con...

The chemical speciation of arsenic in sediments and porewaters of aquifers is the critical factor that determines whether dissolved arsenic accumulates to potentially toxic levels. Sequestration of arsenic in solid phases, which may occur by adsorption or precipitation processes, controls dissolved concentrations. We present synchrotron x-ray absorption spectra of arsenic in shallow aquifer sed...

In this work, mechanical alloying was employed to produce Ti-50Al and Ti-45Al-5Cr (at%) alloys. Alloying was performed in a planetary mill and the alloying time varying from 5 to 70h. Characterization of the powder mixture was performed by X-ray diffraction (XRD), SEM analyses and DTA test, during mechanical alloying and after annealing at 1100°c in vacuum oven. The results showed, after 50h of...