Combined kinetic analysis has been applied for the first time to the thermal degradation of polymeric materials. The combined kinetic analysis allows the determination of the kinetic parameter from the simultaneous analysis of a set of experimental curves recorded under any thermal schedule. Besides, the method does not make any assumption about the kinetic model or activation energy and allows...

The kinetics of N2O decomposition to gaseous nitrogen and oxygen over HZSM-5 catalysts with low content of iron (<400 ppm) under transient and steady-state conditions was investigated in the temperature range of 250–380 8C. The catalysts were prepared from the HZSM-5 with Fe in the framework upon steaming at 550 8C followed by thermal activation in He at 1050 8C. The N2O decomposition began at ...

Ageing and stabilization polymers is a major part of materials science. Aging of polymers defined as a set of chemical and physical transformations, leads to the loss of their set the desired properties. The main role in these transformations belong to chemical processes of degradation and crosslinking of macromolecules. Processes decomposition and structuring polymer conjugates include radical...

ionomers are generally described by copolymers having either acrylic or methacylic acid as one component and the other component is mostly either ethylene or styrene. the objective of this research was to study the thermal behaviour and stability of ionomers of styrene with some alkali metal acrylates. these materials have been synthesized by neutralization of the respective copolymer containin...

magnesium hydroxide nanostructures as an effective flame retardant were synthesized by a facile and rapid microwave reaction. the effect of different surfactants such as cationic, anionic and polymeric on the morphology of magnesium hydroxide nanostructures was investigated. nanostructures were characterized by x-ray diffraction (xrd), scanning electron microscopy (sem) and fourier transform in...