Temperature programmed oxidation (TPO) coupled with in situ Raman spectroscopy has been used as an effective qualitative and quantitative analysis of raw and purified single-walled carbon nanotubes (SWNT) samples. The incorporation of Raman facilitates the identification of the nature of the oxidation peaks present in a TPO profile. Using different samples it was possible to evaluate the potent...

Smooth and aligned single walled carbon nanotube (SWNT) thin films with improved optoelectronic performance are fabricated using a superacid slide casting method. Deposition of as made SWNT thin film on silicon (Si) together with post treatments result in SWNT/Si hybrid solar cells with unprecedented high fill factor of 73.8%, low ideality factor of 1.08 as well as overall dry cell power conver...

The structural and mechanical properties of single-walled carbon nanotubes (SWNTs) make them ideal tips for scanning probe microscopies such as atomic force microscopy (AFM). However, the ideal nanotube probe, which corresponds to an individual SWNT, has been difficult to produce in high yield. To overcome this difficulty, a straightforward and easily implemented method that enables very high-y...

When using single-walled carbon nanotube (SWNT) probes to create AFM images of SWNT samples in tapping mode, elastic deformations of the probe and sample result in a decrease in the apparent width of the sample. Here we show that there are two major mechanisms for this effect, smooth gliding and snapping, and compare their dynamics to the case when a conventional silicon tip is used to image a ...

Abstract Thermal boundary resistance (TBR) between a single-walled carbon nanotube (SWNT) and matrices of solid and liquid argon was investigated by performing classical molecular dynamics simulations. Thermal boundary conductance (TBC), i.e. inverse of TBR, was quantified for a range of nanotube lengths by applying a pico-second heat pulse to the SWNT and observing the relaxation. The SWNT-len...

Interaction between hydrogen molecules and bare as well as functionalized single-wall carbon nanotubes SWNT is investigated using first-principles plane wave method. It is found that the binding energy of the H2 physisorbed on the outer surface of the bare SWNT is very weak, and cannot be enhanced significantly either by increasing the curvature of the surface through radial deformation, or by ...

The reconstitution of apo-glucose oxidase (apo-GOx) on single-walled carbon nanotubes (SWNTs) functionalized with the cofactor, flavin adenine dinucleotide (FAD), greatly improved electron transfer turnover rate of the redox reactions in glucose sensing with glucose sensors. The research reported here is aimed to better understand molecular details of affection of the charging SWNT to the confo...

Abstract The synthesis of ultrathin rhenium disulfide (ReS 2 ) nanoribbons within single-walled carbon nanotubes (SWNTs) has been established. Dirhenium decacarbonyl complex is encapsulated into the SWNTs to provide a source confined atoms, which readily react with iodine form discrete nm-sized clusters iodide [Re 6 I 14 ] 2− embedded in nanotubes. final step accomplished by admitting hydrogen ...

non-isothermal crystallization kinetics of polypropylene (pp) and pp containing 0.5 wt% singlewalled carbon nanotubes (pp/swnt) were studied at various cooling rates using differential scanning calorimetry technique. the non-isothermal melt crystallization data were analyzed according to ozawa and cazé-chuah models. although ozawa model was successful in describing the nonisothermal crystalliza...

Clusters of transition metals, W, Re, and Os, upon encapsulation within a single-walled carbon nanotube (SWNT) exhibit marked differences in their affinity and reactivity with the SWNT, as revealed by low-voltage aberration-corrected high-resolution transmission electron microscopy (AC-HRTEM). Activated by an 80 keV electron beam, W reacts only weakly with the SWNT, Re creates localized defects...